The van der Waal's equation : $\left(P+\frac{a}{4 V^2}\right)\left(V-\frac{b}{2}\right)=\frac{R T}{2}$ is valid for

Adiabatic free expansion of ideal gas must be

$360 \mathrm{~cm}^3$ of a hydrocarbon diffuses in 30 minutes, while under the same conditions $360 \mathrm{~cm}^3$ of $\mathrm{SO}_2$ gas diffuses in one hour. The molecular formula of the hydrocarbon is

An LPG (Liquified Petroleum Gas) cylinder weighs 15.0 kg when empty. When full, it weighs 30.0 kg and shows a pressure of 3.0 atm . In the course of usage at $27^{\circ} \mathrm{C}$, the mass of the full cylinder is reduced to $24 \cdot 2 \mathrm{~kg}$. The volume of the used gas in cubic metre at the normal usage condition ( atm and $27^{\circ} \mathrm{C}$ ) is (assume LPG to be normal butane and it behaves ideally)