For the reaction $R \rightarrow P$, half life is independent of initial concentration of the reactant, $R$. Which one of the following graphs is not correct for the reaction?
For the gaseous reaction, $\mathrm{N}_{2} \mathrm{O}_{5} \longrightarrow 2 \mathrm{NO}_{2}+\frac{1}{2} \mathrm{O}_{2}$
the rate can be expressed as
$ \begin{array}{l} -\frac{d\left[\mathrm{~N}_{2} \mathrm{O}_{5}\right]}{d t}=K_{1}\left[\mathrm{~N}_{2} \mathrm{O}_{5}\right] \\\\ +\frac{d\left[\mathrm{NO}_{2}\right]}{d t}=K_{2}\left[\mathrm{~N}_{2} \mathrm{O}_{5}\right] \\\\ +\frac{d\left[\mathrm{O}_{2}\right]}{d t}=K_{3}\left[\mathrm{~N}_{2} \mathrm{O}_{5}\right] \end{array} $
The correct relation between $K_{1}, K_{2}$ and $K_{3}$
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