1
TG EAPCET 2025 (Online) 4th May Evening Shift
MCQ (Single Correct Answer)
+1
-0

$$ \text { Observe the following complex ions } $$

$$ \begin{array}{cccc} \hline\left[\mathrm{Mn}(\mathrm{CN})_6\right]^{3-} & {\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{3-}} & {\left[\mathrm{CoF}_6\right]^{3-}} & {\left[\mathrm{Co}\left(\mathrm{C}_2 \mathrm{O}_4\right)_3\right]^{3-}} \\ \hline A & B & C & D \\ \hline \end{array} $$

Identify the option in which the unpaired electrons in the complex ions are in correct increasing order

A

$C, A, B, D$

B

$B, A, C, D$

C

$D, A, B, C$

D

$D, B, A, C$

2
TG EAPCET 2025 (Online) 4th May Morning Shift
MCQ (Single Correct Answer)
+1
-0

Which one of the following complex ions is diamagnetic in nature?

A

$\left[\mathrm{CoF}_6\right]^{3-}$

B

$\left[\mathrm{Co}(\mathrm{Ox})_3\right]^{3-}$

C

$\left[\mathrm{Mn}(\mathrm{CN})_6\right]^{3-}$

D

$\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{3-}$

3
TG EAPCET 2025 (Online) 3rd May Evening Shift
MCQ (Single Correct Answer)
+1
-0

Total number of geometrical isomers possible for the complexes $\left[\mathrm{NiCl}_4\right]^{2-}$, $\left[\mathrm{CoCl}_2\left(\mathrm{NH}_3\right)_4\right]^{+}$, $\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_3\left(\mathrm{NO}_2\right)_3\right]$ and $\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5 \mathrm{Cl}\right]^{2+}$ is

A

2

B

3

C

4

D

5

4
TG EAPCET 2025 (Online) 3rd May Morning Shift
MCQ (Single Correct Answer)
+1
-0

Arrange the following complexes in the increasing order of their spin only magnetic moment (in B.M)

I. $\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{4-}$

II. $\left[\mathrm{MnCl}_4\right]^{2-}$

III. $\left[\mathrm{Mn}(\mathrm{CN})_6\right]^{4-}$

IV. $\left.\left[\mathrm{Cr}(\mathrm{NH})_3\right)_6\right]^{3+}$

A

II $<$ IV $<$ I $<$ III

B

III $<$ II $<$ I $<$ IV

C

I $<$ IV $<$ II $<$ III

D

I $<$ III $<$ IV $<$ II

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