p-Block Elements · Chemistry · TS EAMCET

Which among the following oxoacids of phosphorous will have $\mathrm{P}-\mathrm{O}-\mathrm{P}$ bonds?

I. $\mathrm{H}_{4} \mathrm{P}_{2} \mathrm{O}_{5}$

II. $\mathrm{H}_{4} \mathrm{P}_{2} \mathrm{O}_{6}$

III. $\mathrm{H}_{4} \mathrm{P}_{2} \mathrm{O}_{7}$

IV. $\left(\mathrm{HPO}_{3}\right)_{3}$

What are $X$ and $Y$ respectively in the following reactions ?

$ X \stackrel{\mathrm{CO}}{\longleftarrow} \mathrm{~B}_{2} \mathrm{H}_{6} \xrightarrow[\left(\mathrm{C}_{2} \mathrm{H}_{5}\right)_{2} \mathrm{O}]{\mathrm{NaH}} Y $

Which of the following statements are correct?

(i) $\mathrm{CCl}_{4}$ undergoes hydrolysis easily

(ii) Diamond has directional covalent bonds

(iii) Fullerene is thermodynamically most stable allotrope of carbon

(iv) Glass is a man-made silicate

The correct answer is

Observe the following reactions (unbalanced)

$ \begin{array}{r} \mathrm{P}_{2} \mathrm{O}_{3}+\mathrm{H}_{2} \mathrm{O} \longrightarrow X \\ \mathrm{P}_{4} \mathrm{O}_{10}+\mathrm{H}_{2} \mathrm{O} \longrightarrow Y \end{array} $

The number of $\mathrm{P}=\mathrm{O}$ bonds present in $X, Y$ are respectively

Observe the following species.

(i) $\mathrm{NH}_3$

(ii) $\mathrm{AlCl}_3$

(iii) $\mathrm{SnCl}_4$

(iv) $\mathrm{CO}_2$

(v) $\mathrm{Ag}^{+}$

(vi) $ \mathrm{HSO}_{4}^{-} $

How many of the above species act as Lewis acids?

Consider the following reactions (not balanced).

$$ \begin{array}{r} \mathrm{BF}_3+\mathrm{NaH} \xrightarrow{450 \mathrm{~K}} X+\mathrm{NaF} \\ X+\mathrm{H}_2 \mathrm{O} \longrightarrow Y+\mathrm{H}_2 \uparrow \end{array} $$

The correct statements about $X$ and $Y$ are

I. $X$ is an electron deficient molecule.

II. in $X, B-B$ bond is present.

III. $Y$ is a weak tribasic acid.

IV. $Y$ acts as a Lewis acid.

Consider the following reactions.

$$ X+\mathrm{O}_2 \rightarrow \mathrm{Cu}_2 \mathrm{O}+\mathrm{SO}_2, \mathrm{Cu}_2 \mathrm{O}+X \rightarrow \mathrm{Cu}+Y \uparrow $$

The shape of the molecule $Y$ is

Which of the following when subjected to thermal decomposition will liberate dinitrogen ?

(i) Sodium nitrate

(ii) Ammonium dichromate

(iii) Barium azide

The dioxides and monoxides of elements $X$ and $Y$ are amphoteric in nature. $X$ and $Y$ are respectively

Assertion (A) : In group 15 elements nitrogen does not form pentahalides.

Reason (R) : Nitrogen can exhibit +5 oxidation state.

The correct option among the following is

Which of the following reaction represents Deacon's method?

What are the correct statements about the elements of group 13 given below?

(I) The stability of +1 oxidation state follows the order $\mathrm{Tl}>\mathrm{In}>\mathrm{Ga}$.

(II) Boron has the lowest melting point and boiling point as it is a non-metal.

(III) Boron shows a maximum covalency of 4 in its compounds.

(IV) The order of atomic radius is $\mathrm{Ga}>\mathrm{Al}>\mathrm{In}$.

(V) Aluminium is passive to concentrated nitric acid.

Consider the reaction,

$$ \mathrm{P}_4+3 \mathrm{NaOH}+3 \mathrm{H}_2 \mathrm{O} \longrightarrow Q+3 \mathrm{NaH}_2 \mathrm{PO}_2 $$

Identify the reaction in which $Q$ is not the product. (equations are not balanced)