p-Block Elements · Chemistry · TS EAMCET

Which among the following oxoacids of phosphorous will have $\mathrm{P}-\mathrm{O}-\mathrm{P}$ bonds?

I. $\mathrm{H}_{4} \mathrm{P}_{2} \mathrm{O}_{5}$

II. $\mathrm{H}_{4} \mathrm{P}_{2} \mathrm{O}_{6}$

III. $\mathrm{H}_{4} \mathrm{P}_{2} \mathrm{O}_{7}$

IV. $\left(\mathrm{HPO}_{3}\right)_{3}$

What are $X$ and $Y$ respectively in the following reactions ?

$ X \stackrel{\mathrm{CO}}{\longleftarrow} \mathrm{~B}_{2} \mathrm{H}_{6} \xrightarrow[\left(\mathrm{C}_{2} \mathrm{H}_{5}\right)_{2} \mathrm{O}]{\mathrm{NaH}} Y $

Which of the following statements are correct?

(i) $\mathrm{CCl}_{4}$ undergoes hydrolysis easily

(ii) Diamond has directional covalent bonds

(iii) Fullerene is thermodynamically most stable allotrope of carbon

(iv) Glass is a man-made silicate

The correct answer is

Observe the following reactions (unbalanced)

$ \begin{array}{r} \mathrm{P}_{2} \mathrm{O}_{3}+\mathrm{H}_{2} \mathrm{O} \longrightarrow X \\ \mathrm{P}_{4} \mathrm{O}_{10}+\mathrm{H}_{2} \mathrm{O} \longrightarrow Y \end{array} $

The number of $\mathrm{P}=\mathrm{O}$ bonds present in $X, Y$ are respectively

Observe the following species.

(i) $\mathrm{NH}_3$

(ii) $\mathrm{AlCl}_3$

(iii) $\mathrm{SnCl}_4$

(iv) $\mathrm{CO}_2$

(v) $\mathrm{Ag}^{+}$

(vi) $ \mathrm{HSO}_{4}^{-} $

How many of the above species act as Lewis acids?

Consider the following reactions (not balanced).

$$ \begin{array}{r} \mathrm{BF}_3+\mathrm{NaH} \xrightarrow{450 \mathrm{~K}} X+\mathrm{NaF} \\ X+\mathrm{H}_2 \mathrm{O} \longrightarrow Y+\mathrm{H}_2 \uparrow \end{array} $$

The correct statements about $X$ and $Y$ are

I. $X$ is an electron deficient molecule.

II. in $X, B-B$ bond is present.

III. $Y$ is a weak tribasic acid.

IV. $Y$ acts as a Lewis acid.

Consider the following reactions.

$$ X+\mathrm{O}_2 \rightarrow \mathrm{Cu}_2 \mathrm{O}+\mathrm{SO}_2, \mathrm{Cu}_2 \mathrm{O}+X \rightarrow \mathrm{Cu}+Y \uparrow $$

The shape of the molecule $Y$ is

Which of the following when subjected to thermal decomposition will liberate dinitrogen ?

(i) Sodium nitrate

(ii) Ammonium dichromate

(iii) Barium azide