Electrochemistry · Chemistry · TS EAMCET

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MCQ (Single Correct Answer)

1

0.592 g of copper is deposited in 60 minutes by passing

0.5 A current through a solution of copper (II) sulphate. The electro chemical equivalent of copper (II) (in $\mathrm{gC}^{-1}$ ) is

( $F=96500 \mathrm{C} \mathrm{mol}^{-1}$ )

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2
The standard electrode potentials $E^{\circ}(\mathrm{V})$ for $\mathrm{Li}^{+} / \mathrm{Li}, \mathrm{Na}^{+} / \mathrm{Na}$ respectively are
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3

Two statements are given below.

Statement I : Molten NaCl is electrolysed using Pt electrodes. $\mathrm{Cl}_{2}$ is liberated at anode.

Statement II : Aqueous $\mathrm{CuSO}_{4}$ is electrolysed using Pt electrodes. $\mathrm{O}_{2}$ is liberated at cathode.

The correct answer is

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4
The molar conductivity of 0.02 M solution of an electrolyte is $124 \times 10^{-4} \mathrm{~S} \mathrm{~m}^2 \mathrm{~mol}^{-1}$. What is the resistance of same solution (in ohms), kept in a cell of cell constant $129 \mathrm{~m}^{-1}$ ?
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5
If the degree of dissociation of formic acid is $11.0 \%$, the molar conductivity of 0.02 M solution of it is (Given, $\lambda^{\circ}\left(\mathrm{H}^{+}\right)=349.6 \mathrm{~S} \mathrm{~cm}^2 \mathrm{~mol}^{-1}$ $\lambda^{\circ}\left(\mathrm{HCOO}^{-}\right)=54.6 \mathrm{~S} \mathrm{~cm}^2 \mathrm{~mol}^{-1}$ )
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6

Identify the correct statements from the following

(A) At 298 K , the potential of hydrogen electrotle placed in a solution of $\mathrm{pH}=10$, is -0.59 V

(B) The limiting molar conductivity of $\mathrm{Ca}^{2+}$ and $\mathrm{Cl}^{-}$is 119 and $76 \mathrm{~S} \mathrm{~cm}^2 \mathrm{~mol}^{-1}$ respectively. The limiting molar conductivity of $\mathrm{CaCl}_2$ is $195 \mathrm{Scm}^2 \mathrm{~mol}^{-1}$

(C) The correct relationship between $K_C$ and $E_{\text {cell }}^{\ominus}$ is $$ E_{\text {cell }}^\theta=\frac{2303 R T}{n F} \log K_C $$

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