145. Rate constants in the following reaction are Reaction 1 :

$$ A \xrightarrow{\text { Catalyst } 1} P_1, k_1=1 \mathrm{~s}^{-1} $$

Reaction 2 :

$$ A \xrightarrow{\text { Catalyst } 2} P_2, k_2=0.1 \mathrm{~L} \mathrm{~mol}^{-1} \mathrm{~s}^{-1} $$

Reaction 3 :

$$ A \xrightarrow{\text { Catalyst } 3} P_3, k_3=0.01 \mathrm{~L} \mathrm{~mol}^{-1} \mathrm{~s}^{-1} $$

The correct relations between the rate of the reactions at 1 M of $A$ are

Which of the following is a zero order reaction?

The reaction, $2 A \rightarrow 2 B+C$ has a rate constant of $1.2 \times 10^{-2} \mathrm{~s}^{-1}$. Which of the following is correct?

The rate constant of a reaction is increased by 4 times after addition of catalyst to the reaction mixture at the same temperature of $27^{\circ} \mathrm{C}$. The change in the activation energy of this reaction is (Take $\ln (1 / 4)=-1386, R=8.314$ )