Compounds Containing Nitrogen · Chemistry · TS EAMCET

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MCQ (Single Correct Answer)

1

What is the product ' $Z$ ' in the given sequence of reactions?

TG EAPCET 2025 (Online) 4th May Morning Shift Chemistry - Compounds Containing Nitrogen Question 24 English
TG EAPCET 2025 (Online) 4th May Morning Shift
2

What is the major product ' $Z$ ' in the given reaction sequence?

TG EAPCET 2025 (Online) 4th May Morning Shift Chemistry - Compounds Containing Nitrogen Question 23 English

TG EAPCET 2025 (Online) 4th May Morning Shift
3

The reagent which is used to distinguish primary, secondary and tertiary amines from the mixture is

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4

$$ \text { The product ' } C \text { ' in the given reaction sequence is } $$

TG EAPCET 2025 (Online) 2nd May Evening Shift Chemistry - Compounds Containing Nitrogen Question 27 English
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5

The amine/salt of amine which gives positive test with a mixture of chloroform and alcoholic KOH solution is

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6

The major products $P$ and $Q$ from the following reactions are

TG EAPCET 2025 (Online) 2nd May Morning Shift Chemistry - Compounds Containing Nitrogen Question 28 English
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7

What are $X$ and $Y$ respectively in the following reactions?

TG EAPCET 2024 (Online) 10th May Evening Shift Chemistry - Compounds Containing Nitrogen Question 33 English

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8

TG EAPCET 2024 (Online) 10th May Morning Shift Chemistry - Compounds Containing Nitrogen Question 34 English

Conversion of $X$ to $Y$ in the above reaction is

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9

Identify the correct statements about $Z$.



$$ \mathrm{C}_2 \mathrm{H}_5 \mathrm{NH}_2 \xrightarrow[0^{\circ} \mathrm{C}]{\mathrm{NaNO}_2 / \mathrm{HCl}} X \xrightarrow{\mathrm{H}_2 \mathrm{O}} Y \xrightarrow{\mathrm{Cu} / 573 \mathrm{~K}} Z $$

I. $Z$ is an aldehyde.

II. $Z$ undergòes Cannizzaro reaction.

III. $Z$ gives iodoform test.

IV. $Z$ does not give, test with Tollens' reagent.

TG EAPCET 2024 (Online) 9th May Evening Shift
10
Match the following.
List -I (Amine) List -II (pKb value)
A. N,N-dimethyl aniline I. 9.30
B. Aniline II. 8.92
C. N-ethylethanamine III. 9.38
D. N-methylaniline IV. 3.00
The correct answer is
TG EAPCET 2024 (Online) 9th May Evening Shift
11
The $\mathrm{p} K_{\mathrm{a}}$ values of $X, Y, Z$ respectively are $8.3,7.1,10.2$. What are $X, Y, Z$ ?
TG EAPCET 2024 (Online) 9th May Morning Shift
12
The reagents/ chemicals $X$ and $Y$ that convert cyanobenzene to Schiff's base are
TG EAPCET 2024 (Online) 9th May Morning Shift
13
The correct statement(s) of the following is/are (A) Aniline forms a stable benzene diazonium chloride at 285 K . (B) N - phenylethanamide is less reactive towards nitration than aniline. (C) $p-\mathrm{CH}_3 \mathrm{C}_6 \mathrm{H}_4 \mathrm{COCl}$ is Hinsberg reagent.
TG EAPCET 2024 (Online) 9th May Morning Shift
14

$$ \text { The major product ' } Z \text { ' in the reaction sequence is } $$

TS EAMCET 2023 (Online) 14th May Evening Shift Chemistry - Compounds Containing Nitrogen Question 16 English

TS EAMCET 2023 (Online) 14th May Evening Shift
15

Arrange the following in the order of decreasing basicity.

I. $\mathrm{RN}=\mathrm{CH} R^1$

II. $\mathrm{RC} \equiv \mathrm{N}$

III. $\mathrm{RNH}_2$

TS EAMCET 2023 (Online) 14th May Evening Shift
16

Which one of the following gives a foul-smelling substance when treated with chloroform and alcoholic KOH ?

TS EAMCET 2023 (Online) 14th May Evening Shift
17

The sequence of reagents which convert $p$-methyl aniline to $p$-methyl benzoic acid are

TS EAMCET 2023 (Online) 13th May Evening Shift
18

An amine $(X)$ reacts with $p$-toluene sulphonyl chloride to give the product $Y$, which is insoluble in alkali. The product of $X$ with benzoyl chloride is

TS EAMCET 2023 (Online) 13th May Evening Shift
19

$$ \text { In the given reaction, what is } X \text { ? } $$

TS EAMCET 2023 (Online) 13th May Morning Shift Chemistry - Compounds Containing Nitrogen Question 20 English

TS EAMCET 2023 (Online) 13th May Morning Shift
20

Which of the following reactions are used in the preparation of aliphatic primary amines?

I. Gabriel's phthalimide reaction

II. Hoffmann bromamide reaction

III. Carbylamine reaction

IV. Sandmeyer reaction

TS EAMCET 2023 (Online) 13th May Morning Shift
21

In the following sequence of reaction, identify the major product $B$.

TS EAMCET 2023 (Online) 13th May Morning Shift Chemistry - Compounds Containing Nitrogen Question 22 English

TS EAMCET 2023 (Online) 13th May Morning Shift
22

What is the major product ' $R$ ' in the following reaction sequence?

TS EAMCET 2023 (Online) 12th May Evening Shift Chemistry - Compounds Containing Nitrogen Question 29 English
TS EAMCET 2023 (Online) 12th May Evening Shift
23

$$ \text { Identify what is } Y \text { in the following reaction sequence? } $$

TS EAMCET 2023 (Online) 12th May Evening Shift Chemistry - Compounds Containing Nitrogen Question 30 English
TS EAMCET 2023 (Online) 12th May Evening Shift
24
TS EAMCET 2023 (Online) 12th May Morning Shift Chemistry - Compounds Containing Nitrogen Question 31 EnglishConversion of $A$ to $B$ is an example of the reaction
TS EAMCET 2023 (Online) 12th May Morning Shift
25
Identify the product ' $Y$ ' in the following sequence of reactionsTS EAMCET 2023 (Online) 12th May Morning Shift Chemistry - Compounds Containing Nitrogen Question 32 English
TS EAMCET 2023 (Online) 12th May Morning Shift
26

$$ \text { The major product of the following reaction is } $$

TS EAMCET 2022 (Online) 20th July Evening Shift Chemistry - Compounds Containing Nitrogen Question 8 English

TS EAMCET 2022 (Online) 20th July Evening Shift
27

$$ \text { Match the following. } $$

                           List-I                          List-II
(A) Amide (I) Carbylamine reaction
(B) Nitrile (II) Hinsberg's reagent
(C)
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  <mi mathvariant="normal">C</mi>

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<mn>6</mn>

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  <mi mathvariant="normal">H</mi>

</mrow>

<mn>5</mn>

<mrow data-mjx-texclass="ORD">

  <mi data-mjx-auto-op="false">SO</mi>

</mrow>

<mn>2</mn>

<mi data-mjx-auto-op="false">Cl</mi>

<mrow data-mjx-texclass="ORD">

  <mi mathvariant="normal">C</mi>

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<mn>6</mn>

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  <mi mathvariant="normal">H</mi>

</mrow>

<mn>5</mn>

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  <mi data-mjx-auto-op="false">SO</mi>

</mrow>

<mn>2</mn>

<mi data-mjx-auto-op="false">Cl</mi>

C_(6)H_(5)SO_(2)Cl
(III) Hoffmann's bromamide
(D)
<mn>1</mn>

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  <mo>∘</mo>

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<mn>1</mn>

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1^(@)
amine
(IV)
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  <mi data-mjx-auto-op="false">LiAlH</mi>

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<mn>4</mn>

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  <mi data-mjx-auto-op="false">LiAlH</mi>

</mrow>

<mn>4</mn>

LiAlH_(4)

$$ \text { The correct match is } $$

TS EAMCET 2022 (Online) 20th July Morning Shift
28

In the following reaction, the suitable starting reagent $P$ is

TS EAMCET 2022 (Online) 19th July Evening Shift Chemistry - Compounds Containing Nitrogen Question 9 English

TS EAMCET 2022 (Online) 19th July Evening Shift
29

Among the following set of reactions, the most suitable method for preparing secondary amine is

TS EAMCET 2022 (Online) 19th July Morning Shift
30

The major product of the following synthetic sequence is

TS EAMCET 2022 (Online) 18th July Evening Shift Chemistry - Compounds Containing Nitrogen Question 13 English

TS EAMCET 2022 (Online) 18th July Evening Shift
31

Consider following reaction, where

(A) the change in the functional group and

(B) the corresponding change in the hybridisation from starting to the final product $A$ and $B$ are

TS EAMCET 2022 (Online) 18th July Morning Shift Chemistry - Compounds Containing Nitrogen Question 12 English

TS EAMCET 2022 (Online) 18th July Morning Shift
32

The starting material that produce pentanamine by Hoffmann bromamide reaction is

TS EAMCET 2022 (Online) 18th July Morning Shift
33

The major product formed by the reaction of benzylamine with nitrous acid is

TS EAMCET 2020 (Online) 14th September Evening Shift
34

The product formed when aniline is treated with chloroform in the presence of KOH (alcoholic) is

TS EAMCET 2020 (Online) 14th September Morning Shift
35

$$ \text { The major product in the following reactions, is } $$TS EAMCET 2020 (Online) 11th September Evening Shift Chemistry - Compounds Containing Nitrogen Question 2 English

TS EAMCET 2020 (Online) 11th September Evening Shift
36
4-Nitrotoluene (para-nitrotoluene) on reduction with $\mathrm{Fe} / \mathrm{HCl}$ and then electrophilic bromination with an excess amount of $\mathrm{Br}_2$ gives
TS EAMCET 2020 (Online) 11th September Morning Shift
37

$$ \text { What are } X \text { and } Y \text { in the following reaction? } $$

TS EAMCET 2020 (Online) 11th September Morning Shift Chemistry - Compounds Containing Nitrogen Question 5 English

TS EAMCET 2020 (Online) 11th September Morning Shift
38

$$ \text { The major product formed in the following reactions is } $$

TS EAMCET 2020 (Online) 10th September Evening Shift Chemistry - Compounds Containing Nitrogen Question 6 English

TS EAMCET 2020 (Online) 10th September Evening Shift
39

$$ \text { Following transformation can be accomplished by } $$

TS EAMCET 2020 (Online) 10th September Morning Shift Chemistry - Compounds Containing Nitrogen Question 7 English

TS EAMCET 2020 (Online) 10th September Morning Shift