For a first order reaction, a plot of $\ln k\left(Y\right.$-axis) and $\frac{1}{T}$ $(X$-axis) gave the straight line with slope equal to $-10^3 \mathrm{~K}$ and intercept equal to 2.303 ( on $Y$-axis). What is the activation energy ( $E_a$ in $\mathrm{kJ} \mathrm{mol}^{-1}$ ) of the reaction? (Given, $R=8314 \mathrm{JK}^{-1} \mathrm{~mol}^{-1}$ )

If benzene diazonium chloride undergoes first order decomposition at $T(\mathrm{~K})$ with a rate constant of $6.93 \times 10^{-2} \mathrm{~min}^{-1}$, the time for completion of $90 \%$ of the reaction (in min ) is (nearest integer) $(\log 2=0.30$, $\log 3=0.477$ )