Calculate standard enthalpy change of reaction

$$ \mathrm{C}_2 \mathrm{H}_{2(\mathrm{~g})}+\frac{5}{2} \mathrm{O}_{2(\mathrm{~g})} \longrightarrow 2 \mathrm{CO}_{2(\mathrm{~g})}+\mathrm{H}_2 \mathrm{O}_{(\mathrm{l})}, \text { if } $$

$$ \begin{aligned} & \Delta_{\mathrm{f}} \mathrm{H}^{\circ}\left(\mathrm{CO}_2\right)=-393 \mathrm{~kJ} \mathrm{~mol}^{-1} \\ & \Delta_{\mathrm{f}} \mathrm{H}^{\circ}\left(\mathrm{H}_2 \mathrm{O}\right)=-286 \mathrm{~kJ} \mathrm{~mol}^{-1} \\ & \Delta_{\mathrm{f}} \mathrm{H}^{\circ}\left(\mathrm{C}_2 \mathrm{H}_2\right)=227 \mathrm{~kJ} \mathrm{~mol}^{-1} \end{aligned} $$

Which from following formulae is used to find the $\left[\mathrm{OH}^{-}\right]$ion concentration of a weak monoacidic base?

Rate law for the reaction $a A+b B \rightarrow c C+d D$ is $\mathrm{r}=\mathrm{k}[\mathrm{A}][\mathrm{B}]$. Which from following conditions does NOT affect the rate of reaction?

Identify the name of reaction of aryl halide with alkyl halide and sodium metal in dry ether to give substituted aromatic compounds.