1
AIPMT 2012 Mains
MCQ (Single Correct Answer)
+4
-1
Change Language
Four successive members of the first series of the transition metals are listed below. For which one of them the standard potential $$\left( {E_{{M^{2 + }}/M}^o} \right)$$ value has a positive sign?
A
Co (Z = 27)
B
Ni (Z = 28)
C
Cu (Z = 29)
D
Fe (Z = 26)
2
AIPMT 2012 Mains
MCQ (Single Correct Answer)
+4
-1
Change Language
Which one of the following does not correctly represent the correct order of the property indicated against it?
A
Ti < V < Cr < Mn; increasing number of oxidation states
B
Ti3+ < V3+ < Cr3+ < Mn3+ : increasing magnetic moment
C
Ti < V < Cr < Mn : increasing melting points
D
Ti < V < Mn < Cr : increasing 2nd ionization enthalpy
3
AIPMT 2012 Mains
MCQ (Single Correct Answer)
+4
-1
Change Language
In which of the following arrangements the given sequence is not strictly according to the property indicated against it?
A
HF < HCl < HBr < HI : increasing acidic strength
B
H2O < H2S < H2Se < H2Te : increasing pKa values
C
NH3 < PH3 < AsH3 < SbH3 : increasing acidic character
D
CO2 < SiO2 < SnO2 < PbO2 : increasing oxidising power
4
AIPMT 2012 Mains
MCQ (More than One Correct Answer)
+4
-1
Change Language
Activation energy (E$$a$$) and rate constants (k1 and k2) of a chemical reaction at two different temperatures (T1 and T2) are related by
A
$$\ln {{{k_2}} \over {{k_1}}} = - {{{E_a}} \over R}\left( {{1 \over {{T_1}}} - {1 \over {{T_2}}}} \right)$$
B
$$\ln {{{k_2}} \over {{k_1}}} = - {{{E_a}} \over R}\left( {{1 \over {{T_2}}} - {1 \over {{T_1}}}} \right)$$
C
$$\ln {{{k_2}} \over {{k_1}}} = - {{{E_a}} \over R}\left( {{1 \over {{T_2}}} + {1 \over {{T_1}}}} \right)$$
D
$$\ln {{{k_2}} \over {{k_1}}} = {{{E_a}} \over R}\left( {{1 \over {{T_1}}} - {1 \over {{T_2}}}} \right)$$
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