1
AIPMT 2012 Mains
MCQ (Single Correct Answer)
+4
-1
Change Language
The Gibb's energy for the decomposition of Al2O3 at 500oC is as follows
$${2 \over 3}$$ Al2O3 $$ \to $$ $${4 \over 3}$$ Al + O2
$$\Delta $$rG = +960 kJ mol$$-$$1
The potential difference needed for the electrolytic reduction of aluminium oxide (Al2O3) at 500oC is at least
A
4.5 V
B
3.0 V
C
2.5 V
D
5.0 V
2
AIPMT 2012 Mains
MCQ (Single Correct Answer)
+4
-1
Change Language
Standard reduction potentials of the half reactions are given below :
F2(g) + 2e$$-$$ $$ \to $$ 2F$$-$$(aq) ;   Eo = + 2.85 V
Cl2(g) + 2e$$-$$ $$ \to $$ 2Cl$$-$$(aq) ;   Eo = + 1.36 V
Br2(l) + 2e$$-$$ $$ \to $$ 2Br$$-$$(aq) ;   Eo = + 1.06 V
I2(s) + 2e$$-$$ $$ \to $$ 2I$$-$$(aq) ;  Eo = + 0.53 V

The strongest oxidising and reducing agents 23 respectively are
A
F2 and I$$-$$
B
Br2 and Cl$$-$$
C
Cl2 and Br$$-$$
D
Cl2 and I2
3
AIPMT 2012 Mains
MCQ (Single Correct Answer)
+4
-1
Change Language
Vapour pressure of chloroform (CHCl3) and dichloromethane (CH2Cl2) at 25oC are 200 mm Hg and 41.5 mm Hg respectively. Vapour pressure of the solution obtained by mixing 25.5 g of CHCl3 and 40 g of CH2Cl2 at the same temperature will be
(Molecular mass of CHCl3 = 119.5 u and molecular mass of CH2Cl2 = 85 u)
A
173.9 mm Hg
B
615.0 mm Hg
C
90.6 mm Hg
D
285.5 mm Hg
4
AIPMT 2012 Mains
MCQ (Single Correct Answer)
+4
-1
Change Language
An organic compound (C3H9N) (A), when treated with nitrous acid, gave an alcohol and N2 gas was evolved. (A) on warming with CHCl3 and caustic potash gave (C) which on reduction gave isopropylmethylamine. Predict the structure of (A)
A
AIPMT 2012 Mains Chemistry - Organic Compounds Containing Nitrogen Question 31 English Option 1
B
CH3CH2 $$-$$ NH $$-$$ CH3
C
AIPMT 2012 Mains Chemistry - Organic Compounds Containing Nitrogen Question 31 English Option 3
D
CH3CH2CH2 $$-$$ NH2
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