1
AIPMT 2012 Mains
MCQ (Single Correct Answer)
+4
-1
Change Language
In which of the following arrangements the given sequence is not strictly according to the property indicated against it?
A
HF < HCl < HBr < HI : increasing acidic strength
B
H2O < H2S < H2Se < H2Te : increasing pKa values
C
NH3 < PH3 < AsH3 < SbH3 : increasing acidic character
D
CO2 < SiO2 < SnO2 < PbO2 : increasing oxidising power
2
AIPMT 2012 Mains
MCQ (More than One Correct Answer)
+4
-1
Change Language
Activation energy (E$$a$$) and rate constants (k1 and k2) of a chemical reaction at two different temperatures (T1 and T2) are related by
A
$$\ln {{{k_2}} \over {{k_1}}} = - {{{E_a}} \over R}\left( {{1 \over {{T_1}}} - {1 \over {{T_2}}}} \right)$$
B
$$\ln {{{k_2}} \over {{k_1}}} = - {{{E_a}} \over R}\left( {{1 \over {{T_2}}} - {1 \over {{T_1}}}} \right)$$
C
$$\ln {{{k_2}} \over {{k_1}}} = - {{{E_a}} \over R}\left( {{1 \over {{T_2}}} + {1 \over {{T_1}}}} \right)$$
D
$$\ln {{{k_2}} \over {{k_1}}} = {{{E_a}} \over R}\left( {{1 \over {{T_1}}} - {1 \over {{T_2}}}} \right)$$
3
AIPMT 2012 Mains
MCQ (Single Correct Answer)
+4
-1
Change Language
Molar conductivities $$\left( {\Lambda _m^o} \right)$$ at infinite dilution of NaCl, Hcl and CH3COONa are 126.4, 425.9 and 91.0 S cm2 mol$$-$$1 respectively. $$\left( {\Lambda _m^o} \right)$$ for CH3COOH will be
A
425.5 S cm2 mol$$-$$1
B
180.5 S cm2 mol$$-$$1
C
290.8 S cm2 mol$$-$$1
D
390.5 S cm2 mol$$-$$1
4
AIPMT 2012 Mains
MCQ (Single Correct Answer)
+4
-1
Change Language
The Gibb's energy for the decomposition of Al2O3 at 500oC is as follows
$${2 \over 3}$$ Al2O3 $$ \to $$ $${4 \over 3}$$ Al + O2
$$\Delta $$rG = +960 kJ mol$$-$$1
The potential difference needed for the electrolytic reduction of aluminium oxide (Al2O3) at 500oC is at least
A
4.5 V
B
3.0 V
C
2.5 V
D
5.0 V
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