1
AIPMT 2006
MCQ (Single Correct Answer)
+4
-1
Self condensation of two moles of ethyl acetate in presence of sodium ethoxide yields
A
ethyl propionate
B
ethyl butyrate
C
acetoacetic ester
D
methyl acetoacetate
2
AIPMT 2006
MCQ (Single Correct Answer)
+4
-1
EoFe2+/Fe = $$-$$ 0.441 V and EoFe3+/Fe2+ = 0.771 V, the standard EMF of the reaction Fe + 2Fe3+ $$ \to $$ 3Fe2+ will be
A
0.111 V
B
0.330 V
C
1.653 V
D
1.212 V
3
AIPMT 2006
MCQ (Single Correct Answer)
+4
-1
A hypothetical electrochemical cell is shown below.

$$A\left| {{A^ + }\left( {xM} \right)} \right|\left| {{B^ + }\left( {yM} \right)} \right|B$$

The emf measured is + 0.20 V. The cell reaction is
A
A + B+ $$ \to $$ A+ + B
B
A+ + B $$ \to $$ A + B+
C
A+ + e$$-$$ $$ \to $$ A;  B+ + e$$-$$ $$ \to $$ B
D
the cell reaction cannot be predicted.
4
AIPMT 2006
MCQ (Single Correct Answer)
+4
-1
Consider the reaction :  N2(g) + 3H2(g) $$ \to $$ 2NH3(g)

The equality relationship between $${{d\left[ {N{H_3}} \right]} \over {dt}}$$ and $$ - {{d\left[ {{H_2}} \right]} \over {dt}}$$ is
A
$${{d\left[ {N{H_3}} \right]} \over {dt}} = - {{d\left[ {{H_2}} \right]} \over {dt}}$$
B
$${{d\left[ {N{H_3}} \right]} \over {dt}} = - {1 \over 3}{{d\left[ {{H_2}} \right]} \over {dt}}$$
C
$$ + {{d\left[ {N{H_3}} \right]} \over {dt}} = - {2 \over 3}{{d\left[ {{H_2}} \right]} \over {dt}}$$
D
$$ + {{d\left[ {N{H_3}} \right]} \over {dt}} = - {3 \over 2}{{d\left[ {{H_2}} \right]} \over {dt}}$$
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