1
AIPMT 2006
MCQ (Single Correct Answer)
+4
-1
A hypothetical electrochemical cell is shown below.

$$A\left| {{A^ + }\left( {xM} \right)} \right|\left| {{B^ + }\left( {yM} \right)} \right|B$$

The emf measured is + 0.20 V. The cell reaction is
A
A + B+ $$ \to $$ A+ + B
B
A+ + B $$ \to $$ A + B+
C
A+ + e$$-$$ $$ \to $$ A;  B+ + e$$-$$ $$ \to $$ B
D
the cell reaction cannot be predicted.
2
AIPMT 2006
MCQ (Single Correct Answer)
+4
-1
1.00 g of a non-electrolyte solute (molar mass 250 g mol$$-$$1) was dissolved in 51.2 g of benzene. If the freezing point depression constant, Kf of benzene is 5.12 K kg mol$$-$$1, the freezing point of benzene will be lowered by
A
0.2 K
B
0.4 K
C
0.3 K
D
0.5 K
3
AIPMT 2006
MCQ (Single Correct Answer)
+4
-1
In which of the following molecules are all the bonds are not equal?
A
NF3
B
ClF3
C
BF3
D
AlF3
4
AIPMT 2006
MCQ (Single Correct Answer)
+4
-1
The electronegativity difference berween N and F is greater than that between N and H yet the dipole moment of NH3 (1.5D) is larger than that of NF3 (0.2 D). This is because
A
in NH3 the atomic dipole and bond dipole are in the opposite directions whereas in NF3 these are in the same direction
B
in NH3 as well as in NF3 the atomic dipole and bond dipole are in the same direction
C
in NH3 the atomic dipole and bond dipole are in the same direction whereas in NF3 these are in opposite directions
D
in NH3 as well as in NF3 the atomic dipole and bond dipole are in opposite directions.