1
AIPMT 2006
MCQ (Single Correct Answer)
+4
-1
The enthalpy and entropy change for the reaction:
Br2(l) + Cl2(g) $$ \to $$ 2BrCl(g)
are 30 kJ mol$$-$$1 and 105 J K$$-$$1 mol$$-$$1 respectively.
The temperature at which the reaction will be in equilibrium is
A
300 K
B
285.7 K
C
273 K
D
450 K
2
AIPMT 2006
MCQ (Single Correct Answer)
+4
-1
The enthalpy of hydrogenation of cyclohexene is is $$-$$ 119.5 kJ mol$$-$$1. If resonance energy of benzene is $$-$$ 150.4 kJ mol$$-$$1, its enthalpy of hydrogenation would be
A
$$-$$ 358.5 kJ mol$$-$$1
B
$$-$$ 508.9 kJ mol$$-$$1
C
$$-$$ 208.1 kJ mol$$-$$1
D
$$-$$ 269.9 kJ mol$$-$$1
3
AIPMT 2006
MCQ (Single Correct Answer)
+4
-1
Assume each reaction is carried out in an open container. For which reaction will $$\Delta $$H = $$\Delta $$E ?
A
2CO(g) + O2(g) $$ \to $$  2CO2(g)
B
H2(g) + Br2(g) $$ \to $$ 2HBr(g)
C
C(s) + 2H2O(g) $$ \to $$ 2H2(g) + CO2(g)
D
PCl5(g) $$ \to $$ PCl3(g) + Cl2(g)
4
AIPMT 2006
MCQ (Single Correct Answer)
+4
-1
For the reaction :
CH4(g) + 2O2(g) $$\rightleftharpoons$$ CO2(g) + 2H2O(l),
$$\Delta $$Hr = $$-$$ 170.8 kJ mol$$-$$1.
Which of the following statements is not true?
A
The reaction is exothermic.
B
At equilibrium, the concentrations of CO2(g) and H2O(l) are not equal.
C
The equilibrium constant for the reaction is given by Kp = $${{\left[ {C{O_2}} \right]} \over {\left[ {C{H_4}} \right]\left[ {{O_2}} \right]}}$$
D
Addition of CH4(g) or O2(g) at equilibrium will cause a shift to the right.
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