A pump handling a liquid raises its pressure from $$1$$ bar to $$30$$ $$bar.$$ Take the density of the liquid as $$990$$ $$kg/{m^3}$$. The isentropic specific work done by the pump in $$kJ/kg$$ is

Heat and work are

In an experimental set-up, air flows between two stations $$P$$ and $$Q$$ adiabatically. The direction of flow depends on the pressure and temperature conditions maintained at $$P$$ and $$Q$$. The conditions at station $$P$$ are $$150$$ $$kPa$$ and $$350$$ $$K.$$ The temperature at station $$Q$$ is $$300$$ $$K.$$ The following are the properties and relations pertaining to air:

Specific heat at constant pressure, $$${C_p} = 1.005\,\,kJ/kg\,\,K;$$$
Specific heat at constant volume, $$${C_v} = 0.718\,\,kJ/kg\,\,K;$$$
Characteristic gas constant, $$R=0.287$$ $$kJ/kgK.$$
Enthalpy $$h = {C_p}T,$$
Internal energy, $$u = {C_v}T.$$

If the air has to flow from station $$P$$ to station $$Q,$$ the maximum possible value of pressure in $$kPa$$ at station $$Q$$ is close to

In an experimental set-up, air flows between two stations $$P$$ and $$Q$$ adiabatically. The direction of flow depends on the pressure and temperature conditions maintained at $$P$$ and $$Q$$. The conditions at station $$P$$ are $$150$$ $$kPa$$ and $$350$$ $$K.$$ The temperature at station $$Q$$ is $$300$$ $$K.$$ The following are the properties and relations pertaining to air:

Specific heat at constant pressure, $$${C_p} = 1.005\,\,kJ/kg\,\,K;$$$
Specific heat at constant volume, $$${C_v} = 0.718\,\,kJ/kg\,\,K;$$$
Characteristic gas constant, $$R=0.287$$ $$kJ/kgK.$$
Enthalpy $$h = {C_p}T,$$
Internal energy, $$u = {C_v}T.$$

If the pressure at station $$Q$$ is $$50$$ $$kPa,$$ the change in entropy $$\left( {{S_Q} - {S_p}} \right)$$ in $$kJ/kgK$$ is