1
TG EAPCET 2025 (Online) 3rd May Evening Shift
MCQ (Single Correct Answer)
+1
-0

Total number of geometrical isomers possible for the complexes $\left[\mathrm{NiCl}_4\right]^{2-}$, $\left[\mathrm{CoCl}_2\left(\mathrm{NH}_3\right)_4\right]^{+}$, $\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_3\left(\mathrm{NO}_2\right)_3\right]$ and $\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5 \mathrm{Cl}\right]^{2+}$ is

A

2

B

3

C

4

D

5

2
TG EAPCET 2025 (Online) 3rd May Morning Shift
MCQ (Single Correct Answer)
+1
-0

Arrange the following complexes in the increasing order of their spin only magnetic moment (in B.M)

I. $\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{4-}$

II. $\left[\mathrm{MnCl}_4\right]^{2-}$

III. $\left[\mathrm{Mn}(\mathrm{CN})_6\right]^{4-}$

IV. $\left.\left[\mathrm{Cr}(\mathrm{NH})_3\right)_6\right]^{3+}$

A

II $<$ IV $<$ I $<$ III

B

III $<$ II $<$ I $<$ IV

C

I $<$ IV $<$ II $<$ III

D

I $<$ III $<$ IV $<$ II

3
TG EAPCET 2025 (Online) 2nd May Evening Shift
MCQ (Single Correct Answer)
+1
-0

When 100 mL of 0.2 M solution of $\mathrm{CoCl}_3 \cdot x \mathrm{NH}_3$ is treated with excess of $\mathrm{AgNO}_3$ solution, $3.6 \times 10^{22}$ ions are precipitated. The value of $x$ is $\left(N=6 \times 10^{23} \mathrm{~mol}^{-1}\right)$

A

5

B

6

C

4

D

3

4
TG EAPCET 2025 (Online) 2nd May Morning Shift
MCQ (Single Correct Answer)
+1
-0

Which one of the following is not an ambidenate ligand?

A

CN

B

$\mathrm{SCN}^{-}$

C

$\mathrm{SO}_4^{2-}$

D

$\mathrm{NO}_2^{-}$

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