1
TS EAMCET 2023 (Online) 14th May Evening Shift
MCQ (Single Correct Answer)
+1
-0

The sum of oxidation state and co-ordination number of central metal atom is maximum with respect to which of the following complex?

A

$\mathrm{K}_3\left[\mathrm{Cr}\left(\mathrm{C}_2 \mathrm{O}_4\right)_3\right]$

B

$\left[\mathrm{Cr}(\mathrm{CO})_6\right]$

C

$\mathrm{K}_2\left[\mathrm{PtCl}_6\right]$

D

$\mathrm{K}_4\left[\mathrm{Fe}(\mathrm{CN})_6\right]$

2
TS EAMCET 2023 (Online) 14th May Morning Shift
MCQ (Single Correct Answer)
+1
-0

$$ \text { Match the following. } $$

$$ \begin{array}{llll} \hline & \begin{array}{l} \text { List-I } \\ (\text { Complex }) \end{array} & & \begin{array}{l} \text { List-II } \\ \text { (Spin only magnetic } \\ \text { moment) } \end{array} \\ \hline \text { A. } & {\left[\mathrm{CoF}_6\right]^{3-}} & \text { I. } & 0 \\ \hline \text { B. } & {\left[\mathrm{Co}\left(\mathrm{C}_2 \mathrm{O}_4\right)_3\right]^{3-}} & \text { II. } & \sqrt{24} \\ \hline \text { C. } & {\left[\mathrm{FeF}_6\right]^{3-}} & \text { III. } & \sqrt{8} \\ \hline \text { D. } & {\left[\mathrm{Mn}(\mathrm{CN})_6\right]^{3-}} & \text { IV. } & \sqrt{35} \\ \hline & & \text { V. } & \sqrt{15} \\ \hline \end{array} $$

The correct answer is

A

A-V, B-II, C-IV, D-I

B

A-II, B-I, C-IV, D-III

C

A-II, B-I, C-V, D-III

D

A-III, B-II, C-I, D-V

3
TS EAMCET 2023 (Online) 13th May Evening Shift
MCQ (Single Correct Answer)
+1
-0

Identify the correct set for $\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+}$ ion.

(Hybridisation of $\mathrm{Co}^{3+}$, type of complex, number of unpaired electrons in the complex ion respectively.)

A

$d^2 s p^3$, inner orbital complex, zero

B

$s p^3 d^2$, outer orbital complex, three

C

$d^2 s p^3$, inner orbital complex, two

D

$s p^3 d^2$, outer orbital complex, zero

4
TS EAMCET 2023 (Online) 13th May Morning Shift
MCQ (Single Correct Answer)
+1
-0
  • According to Werner's theory, the number of groups bonded to the central metal atom/ion in a coordination complex represent.

A

oxidation state

B

primary valency

C

secondary valency

D

polyhedron

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