1
TS EAMCET 2022 (Online) 20th July Evening Shift
MCQ (Single Correct Answer)
+1
-0

Secondary valences of the following complexes based on their reactions with excess $\mathrm{AgNO}_3$ are

$$ \begin{array}{llc} \hline & \begin{array}{l} \text { Formula of the } \\ \text { complexes } \end{array} & \begin{array}{c} \text { Moles of } \mathrm{AgCl} \text { precipitated } \\ \text { per mole of complex } \end{array} \\ \hline \text { (I) } & \mathrm{CoCl}_3 \cdot 6 \mathrm{H}_2 \mathrm{O} & 3 \\ \hline \text { (II) } & \mathrm{NiCl}_3 \cdot 6 \mathrm{H}_2 \mathrm{O} & 2 \\ \hline \text { (III) } & \mathrm{Co}\left(\mathrm{SO}_4\right) \mathrm{Br} \cdot 5 \mathrm{NH}_3 & 1 \\ \hline \end{array} $$
A
I II III
4 6 6
B
I II III
6 4 4
C
I II III
6 4 6
D
I II III
6 6 6
2
TS EAMCET 2022 (Online) 20th July Morning Shift
MCQ (Single Correct Answer)
+1
-0

The pair in which both the species have same magnetic moment (spin only) is

A

$\left[\mathrm{CoCl}_4\right]^{2-},\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2-}$

B

$\left[\mathrm{Mn}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+},\left[\mathrm{Cr}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}$

C

$\left[\mathrm{Cr}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+},\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}$

D

$\left[\mathrm{Cr}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+},\left[\mathrm{CoCl}_4\right]^{2-}$

3
TS EAMCET 2022 (Online) 19th July Evening Shift
MCQ (Single Correct Answer)
+1
-0

A metal complex absorbed orange light. The colour in which it appears is

A

yellow

B

yellow- green

C

red

D

green - blue

4
TS EAMCET 2022 (Online) 18th July Evening Shift
MCQ (Single Correct Answer)
+1
-0

Among the given complexes the possess " $\mathrm{CO}^{\prime \prime}$ as a bridged ligands are

I. $\left[\mathrm{Co}_2(\mathrm{CO})_8\right]$

II. $\left[\mathrm{Fe}_3(\mathrm{CO})_{12}\right]$

III. $\left[\mathrm{Mn}_2(\mathrm{CO})_{10}\right]$

IV. $\left[\mathrm{Fe}_2(\mathrm{CO})_9\right]$

A

I, II and III

B

II, III and IV

C

I, II and IV

D

I, III and IV

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