Which of the following compounds can form a zwitter ion?

Following solutions were prepared by mixing different volumes of NaOH and HCl of different concentrations :

A. 60 mL $${M \over {10}}$$ HCl + 40 mL $${M \over {10}}$$ NaOH

B. 55 mL $${M \over {10}}$$ HCl + 45 mL $${M \over {10}}$$ NaOH

C. 75 mL $${M \over {5}}$$ HCl + 25 mL $${M \over {5}}$$ NaOH

D. 100 mL $${M \over {10}}$$ HCl + 100 mL $${M \over {10}}$$ NaOH

pH of which one of them will be equal to 1?

In which case is number of molecules of water maximum?

Which one is a wrong statement?