1
AIPMT 2004
MCQ (Single Correct Answer)
+4
-1
If the bond energies of H $$-$$ H, Br $$-$$ Br, and H $$-$$ Br are 433, 192 and 364 kJ mol$$-$$1 respectively, the $$\Delta $$Ho for the reaction

H2(g) + Br2(g) $$ \to $$ 2HBr(g) is
A
$$-$$ 261 kJ
B
+103 kJ
C
+261 kJ
D
$$-$$103 kJ
2
AIPMT 2004
MCQ (Single Correct Answer)
+4
-1
Considering entropy (S) as a thermodynamic parameter, the criterion for the spontaneity of any process is
A
$$\Delta {S_{system}} + \Delta {S_{surroundings}} > 0$$
B
$$\Delta {S_{system}} - \Delta {S_{surroundings}} > 0$$
C
$$\Delta {S_{system}} > 0\,\,\,$$only
D
$$\Delta {S_{surroundings}} > 0$$ only
3
AIPMT 2004
MCQ (Single Correct Answer)
+4
-1
The solubility product of a sparingly soluble salt AX2 is 3.2 $$ \times $$ 10$$-$$11. Its solubility (in moles/L) is
A
5.6 $$ \times $$ 10$$-$$6
B
3.1 $$ \times $$ 10$$-$$4
C
2 $$ \times $$ 10$$-$$4
D
4 $$ \times $$ 10$$-$$4
4
AIPMT 2004
MCQ (Single Correct Answer)
+4
-1
The rapid change of pH near the stoichiometric point of an acid-base titration is the basis of indicator detection. pH of the solution is related to ratio of the concentrations of the conjugate acid (HIn) and base (In$$-$$) forms of the indicator by the expression
A
$$\log {{\left[ {I{n^ - }} \right]} \over {\left[ {HIn} \right]}} = p{K_{In}} - pH$$
B
$$\log {{\left[ {HIn} \right]} \over {\left[ {I{n^ - }} \right]}} = p{K_{In}} - pH$$
C
$$\log {{\left[ {HIn} \right]} \over {\left[ {I{n^ - }} \right]}} = pH - p{K_{In}}$$
D
$$\log {{\left[ {I{n^ - }} \right]} \over {\left[ {HIn} \right]}} = pH - p{K_{In}}$$
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