Calculate dissociation constant of $$0.001 \mathrm{M}$$ weak monoacidic base undergoing $$2 \%$$ dissociation.

Find the rate law for the reaction, $$\mathrm{CHCl}_{3(\mathrm{~g})}+\mathrm{Cl}_{2(\mathrm{~g})} \rightarrow \mathrm{CCl}_{4(\mathrm{~g})}+\mathrm{HCl}_{(\mathrm{g})}$$ if order of reaction with respect to $$\mathrm{CHCl}_{\mathrm{a}(\mathrm{g})}$$ is one and $$\frac{1}{2}$$ with $$\mathrm{Cl}_{2(\mathrm{~g})}$$.

The rate for reaction $$2 \mathrm{~A}+\mathrm{B} \rightarrow$$ product is $$6 \times 10^{-4} \mathrm{~mol} \mathrm{~dm}^{-3} \mathrm{~s}^{-1}$$ Calculate the rate constant if the reaction is first order in $$\mathrm{A}$$ and zeroth order in $$\mathrm{B}$$. [Given $$[\mathrm{A}]=[\mathrm{B}]=0.3 \mathrm{M}]$$

Calculate molar conductivity of $$\mathrm{NH}_4 \mathrm{OH}$$ at infinite dilution if molar conductivities of $$\mathrm{Ba}(\mathrm{OH})_2$$ $$\mathrm{BaCl}_2$$ and $$\mathrm{NH}_4 \mathrm{Cl}$$ at infinite dilution are $$520,280,129 \Omega^{-1} \mathrm{~cm}^2 \mathrm{~mol}^{-1}$$ respectively.