1
MHT CET 2023 14th May Morning Shift
MCQ (Single Correct Answer)
+1
-0

Identify false statement regarding isothermal process from following.

A
System can exchange heat energy with the surrounding.
B
Enthalpy of system remains constant.
C
Temperature of systems remains constant
D
Internal energy of system remint constant
2
MHT CET 2023 14th May Morning Shift
MCQ (Single Correct Answer)
+1
-0

Calculate dissociation constant of $$0.001 \mathrm{M}$$ weak monoacidic base undergoing $$2 \%$$ dissociation.

A
$$4 \times 10^{-7}$$
B
$$2 \times 10^{-6}$$
C
$$2 \times 10^{-7}$$
D
$$1 \times 10^{-7}$$
3
MHT CET 2023 14th May Morning Shift
MCQ (Single Correct Answer)
+1
-0

Find the rate law for the reaction, $$\mathrm{CHCl}_{3(\mathrm{~g})}+\mathrm{Cl}_{2(\mathrm{~g})} \rightarrow \mathrm{CCl}_{4(\mathrm{~g})}+\mathrm{HCl}_{(\mathrm{g})}$$ if order of reaction with respect to $$\mathrm{CHCl}_{\mathrm{a}(\mathrm{g})}$$ is one and $$\frac{1}{2}$$ with $$\mathrm{Cl}_{2(\mathrm{~g})}$$.

A
Rate $$=\mathrm{k}\left[\mathrm{CHCl}_3\right]\left[\mathrm{Cl}_2\right]^{1 / 2}$$
B
Rate $$=\mathrm{k}\left[\mathrm{CHCl}_3\right]^2\left[\mathrm{Cl}_2\right]^{1 / 2}$$
C
Rate $$=\mathrm{k}\left[\mathrm{CHCl}_3\right]^{3 / 2}\left[\mathrm{Cl}_2\right]$$
D
Rate $$=\mathrm{k}\left[\mathrm{CHCl}_3\right]^{1 / 2}\left[\mathrm{Cl}_2\right]$$
4
MHT CET 2023 14th May Morning Shift
MCQ (Single Correct Answer)
+1
-0

The rate for reaction $$2 \mathrm{~A}+\mathrm{B} \rightarrow$$ product is $$6 \times 10^{-4} \mathrm{~mol} \mathrm{~dm}^{-3} \mathrm{~s}^{-1}$$ Calculate the rate constant if the reaction is first order in $$\mathrm{A}$$ and zeroth order in $$\mathrm{B}$$. [Given $$[\mathrm{A}]=[\mathrm{B}]=0.3 \mathrm{M}]$$

A
$$1 \times 10^{-3} \mathrm{~s}^{-1}$$
B
$$2 \times 10^{-3} \mathrm{~s}^{-1}$$
C
$$3 \times 10^{-3} \mathrm{~s}^{-1}$$
D
$$4 \times 10^{-3} \mathrm{~s}^{-1}$$
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