Which one of the following mixtures can be separated by steam distillation technique?

Observe the following data given in the table ( $K_H=$ Henry's law constant)

$$ \begin{aligned} &\begin{array}{ccccc} \hline \text { Gas } & \mathrm{CO}_2 & \mathrm{Ar} & \mathrm{HCHO} & \mathrm{CH}_4 \\ \hline\left(\boldsymbol{K}_{\mathrm{H}} \text { bar at } \mathbf{2 9 8 ~ K}\right) & 1.67 & 40.3 & 1.83 \times 10^{-5} & 0.413 \\ \hline \end{array}\\ &\text { The correct order of their solubility in water is } \end{aligned} $$

The osmotic pressure (in atm) of an aqueous solution containing 0.01 mol of NaCl (degree of dissociation 0.94 ) and 0.03 mol of glucose in 500 mL at $27^{\circ} \mathrm{C}$ is $\left(R=0.082 \mathrm{~L} \mathrm{~atm} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}\right)$

Which of the following solution has highest amount of solute?