$E_{\mathrm{M}^{3}| \mathrm{M}^{2+}}^{\circ}($ in V$)$ is highest for
Identify the correct statements about lanthanoids
I. $\mathrm{Ce}^{4+}$ and $\mathrm{Tb}^{4+}$ act as oxidising agents.
II. $\mathrm{Eu}^{2+}$ and $\mathrm{Yb}^{2+}$ act as oxidising agents.
III. Misch metal is an alloy of $95 \%$ iron and $5 \%$ lanthanoid metal.
IV. $\mathrm{La}^{3+}$ and $\mathrm{Ce}^{4+}$ are diamagnetic in nature.
Match the following
| List I (Industrial process) | List II (Catalyst used) |
| A Ostwald's process | I $\mathrm{CuCl}_2$ |
| B Haber's process | II Zeolites |
| C Deacon's process | III Pt gauge |
| D Cracking of hydrocarbons | IV Fe |
The correct answer is
Observe the following $f$-block elements
$\mathrm{Eu}(Z=63) ; \mathrm{Pu}(Z=94) ; \mathrm{Cf}(Z=98)$;
$\operatorname{Sm}(Z=62) ; \mathrm{Gd}(Z=64) ; \mathrm{Cm}(Z=96)$
How many of the above have half-filled $f$-orbitals in their ground state?
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