The alkane that can be oxidized to the corresponding alcohol by KMnO$$_4$$ as per the equation
is, when :
For the following reaction at $$300 \mathrm{~K}$$
$$\mathrm{A}_2(\mathrm{~g})+3 \mathrm{~B}_2(\mathrm{~g}) \rightarrow 2 \mathrm{AB}_3(\mathrm{~g})$$
the enthalpy change is $$+15 \mathrm{~kJ}$$, then the internal energy change is :
Rate constants of a reaction at $$500 \mathrm{~K}$$ and $$700 \mathrm{~K}$$ are $$0.04 \mathrm{~s}^{-1}$$ and $$0.14 \mathrm{~s}^{-1}$$, respectively; then, activation energy of the reaction is :
(Given: $$\log 3.5=0.5441, \mathrm{R}=8.31 \mathrm{~J} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}$$)
Mass of glucose $$(\mathrm{C}_6 \mathrm{H}_{12} \mathrm{O}_6)$$ required to be dissolved to prepare one litre of its solution which is isotonic with $$15 \mathrm{~g} \mathrm{~L}^{-1}$$ solution of urea $$(\mathrm{NH}_3 \mathrm{CONH}_2)$$ is (Given: Molar mass in $$\mathrm{g} \mathrm{mol}^{-1} \mathrm{C}: 12, \mathrm{H}: 1, \mathrm{O}: 16, \mathrm{~N}: 14$$)