Rate constants of a reaction at $$500 \mathrm{~K}$$ and $$700 \mathrm{~K}$$ are $$0.04 \mathrm{~s}^{-1}$$ and $$0.14 \mathrm{~s}^{-1}$$, respectively; then, activation energy of the reaction is :
(Given: $$\log 3.5=0.5441, \mathrm{R}=8.31 \mathrm{~J} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}$$)
Mass of glucose $$(\mathrm{C}_6 \mathrm{H}_{12} \mathrm{O}_6)$$ required to be dissolved to prepare one litre of its solution which is isotonic with $$15 \mathrm{~g} \mathrm{~L}^{-1}$$ solution of urea $$(\mathrm{NH}_3 \mathrm{CONH}_2)$$ is (Given: Molar mass in $$\mathrm{g} \mathrm{mol}^{-1} \mathrm{C}: 12, \mathrm{H}: 1, \mathrm{O}: 16, \mathrm{~N}: 14$$)
$$\left[\mathrm{Mn}_2(\mathrm{CO})_{10}\right]$$ and $$\left[\mathrm{Co}_2(\mathrm{CO})_8\right]$$ structures have
A. Metal-Metal linkage
B. Terminal CO groups
C. Bridging CO groups
D. Metal in zero oxidation state
Choose the correct answer from the options given below
Methyl group attached to a positively charged carbon atom stabilizes the carbocation due to