What type of following phenomena does the Cannizzaro reaction exhibit?

If $$\overline{\mathrm{a}}, \overline{\mathrm{b}}, \overline{\mathrm{c}}$$ are three vectors, $$|\overline{\mathrm{a}}|=2,|\overline{\mathrm{b}}|=4,|\overline{\mathrm{c}}|=1, |\bar{b} \times \bar{c}|=\sqrt{15}$$ and $$\bar{b}=2 \bar{c}+\lambda \bar{a}$$, then the value of $$\lambda$$ is

The centroid of tetrahedron with vertices at $$\mathrm{A}(-1,2,3), \mathrm{B}(3,-2,1), \mathrm{C}(2,1,3)$$ and $$\mathrm{D}(-1,-2,4)$$ is

Two adjacent sides of a parallelogram $$\mathrm{ABCD}$$ are given by $$\overline{A B}=2 \hat{i}+10 \hat{j}+11 \hat{k}$$ and $$\overline{\mathrm{AD}}=-\hat{\mathrm{i}}+2 \hat{\mathrm{j}}+2 \hat{\mathrm{k}}$$. The side $$\mathrm{AD}$$ is rotated by an acute angle $$\alpha$$ in the plane of parallelogram so that $$\mathrm{AD}$$ becomes $$\mathrm{AD}^{\prime}$$. If $$\mathrm{AD}^{\prime}$$ makes a right angle with side AB, then the cosine of the angle $$\alpha$$ is given by