Identify product '$$B$$' in following sequence of reactions.

2n Propanone $$\mathrm{\buildrel {Ba{{(OH)}_2}} \over \longrightarrow}$$ A $$\mathrm{\mathrel{\mathop{\kern0pt\longrightarrow} \limits_{ - {H_2}O}^\Delta }}$$ nB

Identify rate law expression for $$2 \mathrm{NO}_{(\mathrm{g})}+\mathrm{Cl}_{2(\mathrm{~g})} \rightarrow 2 \mathrm{NOCl}_{(\mathrm{g})}$$ if the reaction is second order in $$\mathrm{NO}$$ and first order in $$\mathrm{Cl}_2$$.

Which among the following solutions has minimum boiling point elevation?

Calculate osmotic pressure of solution of 0.025 mole glucose in $$100 \mathrm{~mL}$$ water at $$300 \mathrm{~K}$$. $$\left[\mathrm{R}=0.082 \mathrm{~atm} \mathrm{dm} \mathrm{mol}^{-1} \mathrm{~K}^{-1}\right]$$