Consider the following.

I. The electron spin quantum number describes the orientation of the spin of the nucleus with respect to the magnetic field.

II. The orbitals represented by the quantum numbers $n=3, l=2, m=+2$ and $n=3, l=2, m=-2$ have the same energy.

III. The energy of a photon is directly proportional to wavelength but inversely proportional to wave number.

IV. Lyman series of lines appear in ultra-violet region.

The correct statements are

The radius of third orbit of hydrogen atom is $R \mathrm{pm}$. The radius of second orbit of $\mathrm{He}^{+}$ion (in pm is)

The threshold frequency of a metal is $10^{15} \mathrm{~s}^{-1}$. The ratio of maximum kinetic energies of the photoelectrons, when the metal is made to strike with radiations of frequencies $1.5 \times 10^{15} \mathrm{~s}^{-1}$ and $2.0 \times 10^{15} \mathrm{~s}^{-1}$ respectively is