1
AIPMT 2008
MCQ (Single Correct Answer)
+4
-1
The bromination of acetone that occurs in acid solution is represented by this equation.
CH3COCH3(aq) + Br2(aq)  $$ \to $$
     CH3COCH2Br(aq) + H+(aq) + Br$$-$$(aq)
These kinetic data were obtained for given reaction concentrations.
Initial concentrations, M
[CH3COCH3 [Br2] [H+]
0.30 0.05 0.05
0.30 0.10 0.05
0.30 0.10 0.10
0.40 0.05 0.20

Initial rate, disappearance of Br2, Ms$$-$$1
5.7$$ \times $$10$$-$$5
5.7$$ \times $$10$$-$$5
1.2$$ \times $$10$$-$$4
3.1$$ \times $$10$$-$$4

Based on these data, the rate equation is
A
Rate = k[CH3COCH3][Br2][H+]2
B
Rate = k[CH3COCH3][Br2][H+]
C
Rate = k[CH3COCH3][H+]
D
Rate = k[CH3COCH3][Br2]
2
AIPMT 2008
MCQ (Single Correct Answer)
+4
-1
The angular shape of ozone molecule (O3) consists of
A
1$$\sigma $$ and 1$$\pi $$ bond
B
2$$\sigma $$ and 1$$\pi $$ bond
C
1$$\sigma $$ and 2$$\pi $$ bonds
D
2$$\sigma $$ and 2$$\pi $$ bonds
3
AIPMT 2008
MCQ (Single Correct Answer)
+4
-1
The correct order of decreasing second ionisation enthalpy of Ti(22), V(23), Cr(24) and Mn(25) is
A
Mn > Cr > Ti > V
B
Ti > V > Cr > Mn
C
Cr > Mn > V > Ti
D
V > Mn > Cr > Ti
4
AIPMT 2008
MCQ (Single Correct Answer)
+4
-1
For the gas phase reaction,

PCl5(g)  $$\rightleftharpoons$$ PCl3(g) + Cl2(g)

which of the following conditions are correct ?
A
$$\Delta $$H < 0 and $$\Delta $$S < 0
B
$$\Delta $$H > 0 and $$\Delta $$S < 0
C
$$\Delta $$H = 0 and $$\Delta $$S < 0
D
$$\Delta $$H > 0 and $$\Delta $$S > 0
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