1
AIPMT 2008
MCQ (Single Correct Answer)
+4
-1
The bromination of acetone that occurs in acid solution is represented by this equation.
CH3COCH3(aq) + Br2(aq)  $$ \to $$
     CH3COCH2Br(aq) + H+(aq) + Br$$-$$(aq)
These kinetic data were obtained for given reaction concentrations.
Initial concentrations, M
[CH3COCH3 [Br2] [H+]
0.30 0.05 0.05
0.30 0.10 0.05
0.30 0.10 0.10
0.40 0.05 0.20

Initial rate, disappearance of Br2, Ms$$-$$1
5.7$$ \times $$10$$-$$5
5.7$$ \times $$10$$-$$5
1.2$$ \times $$10$$-$$4
3.1$$ \times $$10$$-$$4

Based on these data, the rate equation is
A
Rate = k[CH3COCH3][Br2][H+]2
B
Rate = k[CH3COCH3][Br2][H+]
C
Rate = k[CH3COCH3][H+]
D
Rate = k[CH3COCH3][Br2]
2
AIPMT 2008
MCQ (Single Correct Answer)
+4
-1
The correct order of decreasing second ionisation enthalpy of Ti(22), V(23), Cr(24) and Mn(25) is
A
Mn > Cr > Ti > V
B
Ti > V > Cr > Mn
C
Cr > Mn > V > Ti
D
V > Mn > Cr > Ti
3
AIPMT 2008
MCQ (Single Correct Answer)
+4
-1
How many moles of lead (II) chloride will be formed from a reaction between 6.5 g of PbO and 3.2 g HCl ?
A
0.011
B
0.029
C
0.044
D
0.333
4
AIPMT 2008
MCQ (Single Correct Answer)
+4
-1
What volume of oxygen gas (O2) measuread at 0oC and 1 atm, is needed to burn completely 1 L of propane gas (C3H8) measured under the same conditions ?
A
5 L
B
10 L
C
7 L
D
6 L