1
AIPMT 2003
MCQ (Single Correct Answer)
+4
-1
Which one of the following statements is not correct for sigma- and pi- bonds formed between two carbon atoms?
A
sigma-bond is stronger than a pi-bond.
B
Bond energies of sigma- and pi-bonds are of the order of 264 kJ/mol and 347 kJ/mol, respectively
C
Free rotation of atoms about a sigma-bond is allowed but not in case of a pi-bond.
D
Sigma-bond determines the direction between carbon atoms but a pi-bond has no primary effect in this regard.
2
AIPMT 2003
MCQ (Single Correct Answer)
+4
-1
For the reaction,
C3H8(g) + 5O2(g) $$ \to $$ 3CO2(g) + 4H2O(l)
at constant temperature, $$\Delta $$H $$-$$ $$\Delta $$E is
A
+ RT
B
$$-$$3RT
C
+ 3RT
D
$$-$$ RT
3
AIPMT 2003
MCQ (Single Correct Answer)
+4
-1
The densities of graphite and diamond at 298 K are 2.25 and 3.31 g cm$$-$$3, respectively. If the standard free energy difference $$\left( {\Delta {G^o}} \right)$$ is equal to 1895 J mol$$-$$1, the pressure at which graphite will be transformed into diamond at 298 K is
A
11.14 $$ \times $$ 108 Pa
B
11.14 $$ \times $$ 107 Pa
C
11.14 $$ \times $$ 106 Pa
D
11.14 $$ \times $$ 105 Pa
4
AIPMT 2003
MCQ (Single Correct Answer)
+4
-1
For which one of the following equations is $$\Delta $$Horeact equal to $$\Delta $$Hof for the product ?
A
Xe(g) + 2F2(g) $$ \to $$ XeF4(g)
B
2CO(g) + O2(g) $$ \to $$ 2CO2(g)
C
N2(g) + O3(g) $$ \to $$ N2O3(g)
D
CH4(g) + 2Cl2(g) $$ \to $$ CH2Cl2(l) + 2HCl(g)
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