1
AIPMT 2009
MCQ (Single Correct Answer)
+4
-1
Half-life period of a first order reaction is 1386 seconds. The specific rate constant of the reaction is
A
0.5 $$ \times $$ 10$$-$$2 s$$-$$1
B
0.5 $$ \times $$ 10$$-$$3 s$$-$$1
C
5.0 $$ \times $$ 10$$-$$2 s$$-$$1
D
5.0 $$ \times $$ 10$$-$$3 s$$-$$1.
2
AIPMT 2009
MCQ (Single Correct Answer)
+4
-1
Propionic acid with Br2/P yields a dibromo product. Its structure would be
A
AIPMT 2009 Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 58 English Option 1
B
CH2(Br) $$-$$ CH2 $$-$$ COBr
C
AIPMT 2009 Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 58 English Option 3
D
CH2(Br) $$-$$ CH(Br) $$-$$ COOH
3
AIPMT 2009
MCQ (Single Correct Answer)
+4
-1
In the reaction,
BrO$$_{3(aq)}^ - $$ + 5Br$$_{(aq)}^ - $$ + 6H+ $$ \to $$ 3Br2(l) + 3H2O(l).
The rate of appearance of bromine (Br2) is related to rate of disappearance of bromide ions as
A
$${{d\left[ {B{r_2}} \right]} \over {dt}} = - {5 \over 3}{{d\left[ {B{r^ - }} \right]} \over {dt}}$$
B
$${{d\left[ {B{r_2}} \right]} \over {dt}} = {5 \over 3}{{d\left[ {B{r^ - }} \right]} \over {dt}}$$
C
$${{d\left[ {B{r_2}} \right]} \over {dt}} = {3 \over 5}{{d\left[ {B{r^ - }} \right]} \over {dt}}$$
D
$${{d\left[ {B{r_2}} \right]} \over {dt}} = - {3 \over 5}{{d\left[ {B{r^ - }} \right]} \over {dt}}$$
4
AIPMT 2009
MCQ (Single Correct Answer)
+4
-1
For the reaction A + B $$ \to $$ products, it is observed that

(i)  on doubling the initial concentration of A only, the rate of reaction is also doubled and
(ii)  on doubling the initial concentration of both A and B, there is a change by a factor of 8 in the rate of the reaction.

The rate of this reaction is given by
A
rate = k[A]2 [B]2
B
rate = k[A] [B]2
C
rate = k[A] [B]
D
rate = k[A]2 [B]