1
AIPMT 2007
MCQ (Single Correct Answer)
+4
-1
The reaction of hydrogen and iodine monochloride is given as :
H2(g) + 2ICl(g) $$ \to $$ 2HCl(g) + I2(g)
This reaction is of first order with respect to H2(g) and ICl(g),
following mechanisms were proposed.

Mechanism A :
     H2(g) + 2ICl(g) $$ \to $$ 2HCl(g) + I2(g)
Mechanism B :
     H2(g) + ICl(g) $$ \to $$ HCl(g) + HI(g) ; slow
     HI(g) + ICl(g) $$ \to $$ HCl(g) + I2(g) ; fast

Which of the above mechanism(s) can be consistent with the given information about the reaction?
A
A and B both
B
Neither A nor B
C
A only
D
B only
2
AIPMT 2007
MCQ (Single Correct Answer)
+4
-1
Consider the following reactions :
(i) H+(aq) + OH$$-$$(aq) = H2O(l),  $$\Delta $$H = $$-$$ X1 kJ mol$$-$$1
(ii) H2(g) + 1/2O2(g) = H2O(l),   $$\Delta $$H = $$-$$ X2 kJ mol$$-$$1
(iii) CO2(g) + H2(g) = CO(g) + H2O(l),  $$\Delta $$H = $$-$$ X3 kJ mol$$-$$1
(iv) C2H2(g) + 5/2O2(g) = 2CO2(g) + H2O(l),    $$\Delta $$H = +X4 kJ mol$$-$$1

Enthalpy of formation of H2O(l) is
A
+X3 kJ mol$$-$$1
B
$$-$$X4 kJ mol$$-$$1
C
+X1 kJ mol$$-$$1
D
$$-$$X2 kJ mol$$-$$1
3
AIPMT 2007
MCQ (Single Correct Answer)
+4
-1
An element, X has the following isotopic composition:
200X : 90%  199X : 8.0%  202X : 2.0%

The weighted average atomic mass of the naturally occuring element X is closest to
A
201 amu
B
202 amu
C
199 amu
D
200 amu
4
AIPMT 2007
MCQ (Single Correct Answer)
+4
-1
Consider the following sets of quantum numbers :

n l m s
(i) 3 0 0 +1/2
(ii) 2 2 1 +1/2
(iii) 4 3 -2 -1/2
(iv) 1 0 -1 -1/2
(v) 3 2 3 +1/2


Which of the following sets of quantum number is not possible ?
A
(i), (ii), (iii) and (iv)
B
(ii), (iv) and (v)
C
(i) and (iii)
D
(ii), (iii) and (iv)
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