1
AIPMT 2007
MCQ (Single Correct Answer)
+4
-1
The reaction of hydrogen and iodine monochloride is given as :
H2(g) + 2ICl(g) $$ \to $$ 2HCl(g) + I2(g)
This reaction is of first order with respect to H2(g) and ICl(g),
following mechanisms were proposed.

Mechanism A :
     H2(g) + 2ICl(g) $$ \to $$ 2HCl(g) + I2(g)
Mechanism B :
     H2(g) + ICl(g) $$ \to $$ HCl(g) + HI(g) ; slow
     HI(g) + ICl(g) $$ \to $$ HCl(g) + I2(g) ; fast

Which of the above mechanism(s) can be consistent with the given information about the reaction?
A
A and B both
B
Neither A nor B
C
A only
D
B only
2
AIPMT 2007
MCQ (Single Correct Answer)
+4
-1
If 60% of a first order reaction was completed in 60 minutes, 50% of the same reaction would be completed in approximately
(log 4 = 0.60, log 5 = 0.69)
A
45 minutes
B
60 minutes
C
40 minutes
D
50 minutes
3
AIPMT 2007
MCQ (Single Correct Answer)
+4
-1
Which of the following anions is present in the chain structure of silicates?
A
(Si2O$$_5^{2 - }$$)n
B
(SiO$$_3^{2 - }$$)n
C
SiO$$_4^{4 - }$$
D
Si2O$$_7^{6 - }$$
4
AIPMT 2007
MCQ (Single Correct Answer)
+4
-1
Consider the following reactions :
(i) H+(aq) + OH$$-$$(aq) = H2O(l),  $$\Delta $$H = $$-$$ X1 kJ mol$$-$$1
(ii) H2(g) + 1/2O2(g) = H2O(l),   $$\Delta $$H = $$-$$ X2 kJ mol$$-$$1
(iii) CO2(g) + H2(g) = CO(g) + H2O(l),  $$\Delta $$H = $$-$$ X3 kJ mol$$-$$1
(iv) C2H2(g) + 5/2O2(g) = 2CO2(g) + H2O(l),    $$\Delta $$H = +X4 kJ mol$$-$$1

Enthalpy of formation of H2O(l) is
A
+X3 kJ mol$$-$$1
B
$$-$$X4 kJ mol$$-$$1
C
+X1 kJ mol$$-$$1
D
$$-$$X2 kJ mol$$-$$1