For the gaseous reaction, $\mathrm{N}_{2} \mathrm{O}_{5} \longrightarrow 2 \mathrm{NO}_{2}+\frac{1}{2} \mathrm{O}_{2}$
the rate can be expressed as
$ \begin{array}{l} -\frac{d\left[\mathrm{~N}_{2} \mathrm{O}_{5}\right]}{d t}=K_{1}\left[\mathrm{~N}_{2} \mathrm{O}_{5}\right] \\\\ +\frac{d\left[\mathrm{NO}_{2}\right]}{d t}=K_{2}\left[\mathrm{~N}_{2} \mathrm{O}_{5}\right] \\\\ +\frac{d\left[\mathrm{O}_{2}\right]}{d t}=K_{3}\left[\mathrm{~N}_{2} \mathrm{O}_{5}\right] \end{array} $
The correct relation between $K_{1}, K_{2}$ and $K_{3}$
Match the following
| List I (Industrial process) | List II (Catalyst used) |
| A Ostwald's process | I $\mathrm{CuCl}_2$ |
| B Haber's process | II Zeolites |
| C Deacon's process | III Pt gauge |
| D Cracking of hydrocarbons | IV Fe |
The correct answer is
$\mathrm{C}+$ Conc. $\mathrm{H}_{2} \mathrm{SO}_{4} \xrightarrow{\Delta} X+Y+\mathrm{H}_{2} \mathrm{O}$
$X$ and $Y$ in the above reaction are
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