Chemistry
At $T(K)$ the equilibrium constants for the following two reactions are given below
$ 2 A(g) \rightleftharpoons B(g)+C(g) ; K_{1}=16 $
$ 2 B(g)+C(g) \rightleftharpoons 2 D(g) ; K_{2}=25 $
What is the value of equilibrium constant $(K)$ for the reaction given below at $T(K)$ ?
$ A(g)+\frac{1}{2} B(g) \rightleftharpoons D(g) $
Match the following
List I (Alloy) | List II (Use) |
A Li-Pb | I. In aircraft construction |
B Be-Cu | II. To make bearings for motor engines |
C Mg-Al | III. To make tetraethyl lead |
D Na-Pb | IV. To make high strength springs |
The correct answer is
Consider the following carbocations.
Arrange the above carbocations in the order of decreasing stability
Consider the following reaction sequence
$ \text { 2-methylpropane } \xrightarrow{\mathrm{KMnO}_{4}} X \xrightarrow[358 \mathrm{~K}]{20 \% \mathrm{H}_3 \mathrm{PO}_4} Y \xrightarrow[\text { (ii) } \mathrm{Zn} / \mathrm{H}_{2} \mathrm{O}]{\text { (i) } \mathrm{O}_{3}} A+B \text {. } $
What are $A$ and $B$ ?
Identify the end product $(Z)$ in the sequence of the following reactions.
At 300 K , the vapour pressure of toluene and benzene are 3.63 kPa and 9.7 kPa respectively. What is the composition of vapour in equilibrium with the solution containing 0.4 mole fraction of toluene?
(Assume the solution is ideal)
0.592 g of copper is deposited in 60 minutes by passing
0.5 A current through a solution of copper (II) sulphate. The electro chemical equivalent of copper (II) (in $\mathrm{gC}^{-1}$ ) is
( $F=96500 \mathrm{C} \mathrm{mol}^{-1}$ )
For the gaseous reaction, $\mathrm{N}_{2} \mathrm{O}_{5} \longrightarrow 2 \mathrm{NO}_{2}+\frac{1}{2} \mathrm{O}_{2}$
the rate can be expressed as
$ \begin{array}{l} -\frac{d\left[\mathrm{~N}_{2} \mathrm{O}_{5}\right]}{d t}=K_{1}\left[\mathrm{~N}_{2} \mathrm{O}_{5}\right] \\\\ +\frac{d\left[\mathrm{NO}_{2}\right]}{d t}=K_{2}\left[\mathrm{~N}_{2} \mathrm{O}_{5}\right] \\\\ +\frac{d\left[\mathrm{O}_{2}\right]}{d t}=K_{3}\left[\mathrm{~N}_{2} \mathrm{O}_{5}\right] \end{array} $
The correct relation between $K_{1}, K_{2}$ and $K_{3}$
Match the following
List I (Industrial process) | List II (Catalyst used) |
A Ostwald's process | I $\mathrm{CuCl}_2$ |
B Haber's process | II Zeolites |
C Deacon's process | III Pt gauge |
D Cracking of hydrocarbons | IV Fe |
The correct answer is
$\mathrm{C}+$ Conc. $\mathrm{H}_{2} \mathrm{SO}_{4} \xrightarrow{\Delta} X+Y+\mathrm{H}_{2} \mathrm{O}$
$X$ and $Y$ in the above reaction are
Which among the following oxoacids of phosphorous will have $\mathrm{P}-\mathrm{O}-\mathrm{P}$ bonds?
I. $\mathrm{H}_{4} \mathrm{P}_{2} \mathrm{O}_{5}$
II. $\mathrm{H}_{4} \mathrm{P}_{2} \mathrm{O}_{6}$
III. $\mathrm{H}_{4} \mathrm{P}_{2} \mathrm{O}_{7}$
IV. $\left(\mathrm{HPO}_{3}\right)_{3}$
Observe the following $f$-block elements
$\mathrm{Eu}(Z=63) ; \mathrm{Pu}(Z=94) ; \mathrm{Cf}(Z=98)$;
$\operatorname{Sm}(Z=62) ; \mathrm{Gd}(Z=64) ; \mathrm{Cm}(Z=96)$
How many of the above have half-filled $f$-orbitals in their ground state?
What is the IUPAC name of the product $Y$ in the given reaction sequence?
What is the value of ' $n$ ' in ' $Z$ ' of the following sequence?
Lauryl alcohol $\xrightarrow{\mathrm{H}_{2} \mathrm{SO}_{4}}$
( $X$ )
Lauryl hydrogen sulphate $\xrightarrow{\mathrm{NaOH}(a q)}$
( $Y$ )
$ \mathrm{CH}_{3}-\left(\mathrm{CH}_{2}\right)_{n}-\mathrm{CH}_{2} \mathrm{OSO}_{3} \mathrm{Na} $
(Z)
Sodium lauryl sulphate
What is ' $Z$ ' in the given sequence of reactions?
What is the % carbon in the product ' $Z$ ' formed in the reaction?
Match the following
The correct answer is
What are $Y$ and $Z$ respectively in the given reaction sequence?
What is $C$ in the given sequence of reactions?
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Mathematics
$f(x)=a x^{2}+b x+c$ is an even function and
$g(x)=p x^{3}+q x^{2}+r x$ is an odd function.
If $h(x)=f(x)+g(x)$ and $h(-2)=0$, then $8 p+4 q+2 r=$
If a random variable $X$ has the following probability distribution, then its variance is
X = x | 1 | 3 | 5 | 2 |
P(X = x) | $3 K^2$ | K | $K^2$ | 2K |
Physics
The maximum horizontal range of a ball projected from the ground is 32 m . If the ball is thrown with the same speed horizontally from the top of a tower of . height 25 m , the maximum horizontal distance covered by the ball is
(Acceleration due to gravity $=10 \mathrm{~ms}^{-2}$ )
A body of mass $m$ and radius $r$ rolling horizontally $m$ an inclined plane to a vertical
a velocity $v$ rolls up an height $\frac{v^{2}}{g}$. The body is
An object of mass $m$ at a distance of $20 R$ from the centre of a planet of mass $M$ and radius $R$ has an initity velocity $u$. The velocity with which the object hits the surface of the planet is
( $G$-Universal gravitational constant)
Two closed pipes when sounded simultaneously in their fundamental modes produce 6 beats per second. If the length of the shorter pipe is 150 cm , then the length of the longer pipe is
(Speed of sound in air $=336 \mathrm{~ms}^{-1}$ )
Match the devices given in List-I with their uses given in List-II.
List-I | List -II |
a Transistor | e Filter circuit |
b Diode | f Voltage regulator |
c Zener diode | g Rectifier |
d Capacitor | h Amplifier |
The correct answer is
To get output 1 for the following logic circuit, the correct choice of the inputs is