Chemistry
List I (Element) | List II (Block) |
A Ra | I p - block |
B Uuq | II s- block |
C Ds | III f - block |
D Fm | IV d - block |
Consider the following reactions (not balanced).
$$ \begin{array}{r} \mathrm{BF}_3+\mathrm{NaH} \xrightarrow{450 \mathrm{~K}} X+\mathrm{NaF} \\ X+\mathrm{H}_2 \mathrm{O} \longrightarrow Y+\mathrm{H}_2 \uparrow \end{array} $$
The correct statements about $X$ and $Y$ are
I. $X$ is an electron deficient molecule.
II. in $X, B-B$ bond is present.
III. $Y$ is a weak tribasic acid.
IV. $Y$ acts as a Lewis acid.
The IUPAC name of the following compound is
The functional groups present in the product ' $X$ ' of the reaction given below are
Identify the major product $(P)$ in the following reaction sequence.
$$ \left(\mathrm{CH}_3\right)_3 \mathrm{CBr} \xrightarrow[\text { KOH, } \Delta]{\text { Alcoholic }} X \xrightarrow{\mathrm{HBr}} P $$
What is the percentage of carbon in the product ' $X$ ' formed in the given reaction?
$+\mathrm{C}_2 \mathrm{H}_5 \mathrm{Cl} \xrightarrow[\mathrm{AlCl}_3]{\text { Anhydrous }} X$
[A₂]₀ | [B₂]₀ | Initial rate of formation of AB (mol L⁻¹ s⁻¹) |
0.1 M | 0.1 M | 2.5 × 10⁻⁴ |
0.2 M | 0.1 M | 5.0 × 10⁻⁴ |
0.2 M | 0.1 M | 1.0 × 10⁻³ |
Adsorption of a gas a solid adsorbent follows. Freundlich adsorption isotherm. If $x$ is the mass of the gas adsorbed on mass ' $m$ ' of the adsorbent at pressure $p$. From the graph given extent of adsorption is proportional to
Consider the following reactions.
$$ X+\mathrm{O}_2 \rightarrow \mathrm{Cu}_2 \mathrm{O}+\mathrm{SO}_2, \mathrm{Cu}_2 \mathrm{O}+X \rightarrow \mathrm{Cu}+Y \uparrow $$
The shape of the molecule $Y$ is
$Y$ in the given sequence of reactions is
$$ \begin{gathered} \mathrm{P}_4+x \mathrm{NaOH}+y \mathrm{H}_2 \mathrm{O} \xrightarrow{\mathrm{CO}_2} X+z \mathrm{NaH}_2 \mathrm{PO}_2 \\ X+\mathrm{CuSO}_4 \longrightarrow Y+\mathrm{H}_2 \mathrm{SO}_4 \end{gathered} $$
$\mathrm{Pt}+3: 1$ mixture of $\left(\right.$ Conc. $\mathrm{HCl}+$ conc. $\left.\mathrm{HNO}_3\right) \rightarrow[\mathrm{X}]^{2-}$
What is the oxidation state of Pt in $[\mathrm{X}]^{2-}$ complex ion ?
List I (Type of drug) | List II (Examaple) |
A Antacid | I Serotonin |
B Antihistamine | II Seldane |
C Tranquiliser | III Ranitidine |
D Antibiotic | IV Chloramphenicol |
Identify the correct statements about $Z$.
$$ \mathrm{C}_2 \mathrm{H}_5 \mathrm{NH}_2 \xrightarrow[0^{\circ} \mathrm{C}]{\mathrm{NaNO}_2 / \mathrm{HCl}} X \xrightarrow{\mathrm{H}_2 \mathrm{O}} Y \xrightarrow{\mathrm{Cu} / 573 \mathrm{~K}} Z $$
I. $Z$ is an aldehyde.
II. $Z$ undergòes Cannizzaro reaction.
III. $Z$ gives iodoform test.
IV. $Z$ does not give, test with Tollens' reagent.
Assertion (A) : Aldehydes are more reactive than ketones towards nucleophilic addition reactions
Reason (R) : In aldehydes, carbonyl carbon is less electrophilic compared to ketones.
The correct answer is
Arrange the following in the correct order of their boiling points.
What is the major product $Z$ in the given reaction sequence?
$$ \left(\mathrm{CH}_3\right)_2 \mathrm{C}=\mathrm{O} \xrightarrow[\text { (ii) } 2 \mathrm{H}_2 \mathrm{O}^{+}]{(\mathrm{i}) \mathrm{C}_2 \mathrm{H}_5 \mathrm{MgBr}} \xrightarrow[\Delta]{\substack{\text { (i) } \mathrm{OOCl}_2 \\ \text { (ii) } \mathrm{CH}_3 \mathrm{ONa}}} Y \xrightarrow[\text { Peroxide }]{\mathrm{HBr}} Z $$
List -I (Amine) | List -II (pKb value) |
A. N,N-dimethyl aniline | I. 9.30 |
B. Aniline | II. 8.92 |
C. N-ethylethanamine | III. 9.38 |
D. N-methylaniline | IV. 3.00 |
Mathematics
If $\mathrm{A}=\left[\begin{array}{lll}1 & 2 & 2 \\ 3 & 2 & 3 \\ 1 & 1 & 2\end{array}\right]$ and $\mathrm{A}^{-1}=\left[\begin{array}{lll}a_{11} & a_{12} & a_{13} \\ a_{21} & a_{22} & a_{23} \\ a_{31} & a_{32} & a_{33}\end{array}\right]$, then $\sum_{\substack{1 \leq i \leq 3 \\ 1 \leq j \leq 3}} a_{i j}=$
$\alpha, \beta, \gamma, 2$ and $\varepsilon$ are the roots of the equation
$$ \begin{aligned} & \alpha, \beta, \gamma+4 x^4-13 x^3-52 x^2+36 x+144=0 . \text { If } \\ & \alpha<\beta<\gamma<2<\varepsilon \text {, then } \alpha+2 \beta+3 \gamma+5 \varepsilon= \end{aligned} $$
List I | List II |
(A) sinh x | (I) Domains is (-1,1), even function |
(B) sec hx | (II) Domain is [1,∞), neither even nor odd function |
(C) tan hx | (III) Even function |
(D) cosec h⁻¹x | (IV) Range is R, odd function |
(V) Range is (-1,1), odd function |
The variance of the following continuous frequency distribution is
Classinterval | 0-4 | 4-8 | 8-12 | 12-16 |
Frequency | 2 | 3 | 2 | 1 |
Define $ f: R \rightarrow R $ by $ f(x)=\left\{\begin{array}{cl}\frac{1-\cos 4 x}{x^{2}}, & x < 0 \\ a, & x=0 \\ \frac{\sqrt{x}}{\sqrt{16+\sqrt{x}}-4}, & x > 0\end{array}\right. $
Then, the value of $ a $ so that $ f $ is continuous at $ x=0 $ is
$ \int_{\frac{-3}{4}}^{\frac{\pi-6}{8}} \log (\sin (4 x+3)) d x= $
Physics
The potential difference $V$ across the filament of the bulb shown in the given Wheatstone bridge varies as $V=i(2 i+1)$, where $i$ is the current in ampere through the filament of the bulb. The emf of the battery $V_a$, so that the bridge become balanced is

A zener diode of zener voltage 30 V is connected in circuit as shown in the figure. The maximum current through the zener diode is
