1
COMEDK 2025 Evening Shift
MCQ (Single Correct Answer)
+1
-0
An optically active compound $[\mathrm{X}]$ (Molecular formula $\mathrm{C}_8 \mathrm{H}_{11} \mathrm{~N}$ ) reacts with $\mathrm{CHCl}_3$ / Ethanolic KOH on heating to form an isocyanide. On reaction with $\mathrm{NaNO}_2 / \mathrm{HCl}$, it yields an alcohol with liberation of $\mathrm{N}_2$. Identify the compound $[\mathrm{X}]$.
A
2-Ethylaniline.
B
1-Phenylethanamine.
C
3, 4-Dimethylaniline.
D
2, 4-Dimethylaniline.
2
COMEDK 2025 Evening Shift
MCQ (Single Correct Answer)
+1
-0
Choose the correct statement from the options given
A
The decreasing order of basic nature of the following amines is: Methylamine $>$ Dimethylamine $>$ Trimethylamine $>$ Aniline.
B
The intermolecular bonding in primary amines is stronger than in secondary amines.
C
Benzene diazonium chloride when reacted with Aniline in presence of dil. HCl at 273 K yields $\mathrm{C}_6 \mathrm{H}_5-\mathrm{N}=\mathrm{N}-\mathrm{NH}-\mathrm{C}_6 \mathrm{H}_5$
D
On heating an aliphatic primary amine with $\mathrm{CHCl}_3$ in presence of Ethanolic KOH , a Nitrile is formed
3
COMEDK 2025 Evening Shift
MCQ (Single Correct Answer)
+1
-0
The number of electrons with azimuthal quantum numbers $l=1$ and $l=2$ for Cr in the ground state electronic configurations are respectively. [Given: $\mathrm{Cr}(\mathrm{Z}=24)$ ]
A
5 and 16
B
12 and 5
C
12 and 8
D
12 and 16
4
COMEDK 2025 Evening Shift
MCQ (Single Correct Answer)
+1
-0
The ratio of the difference between the radii of $3^{\text {rd }}$ and $4^{\text {th }}$ orbits of the $\mathrm{He}^{+}$and those of $\mathrm{Li}^{2+}$ is:
A
$2: 3$
B
$3: 1$
C
$1: 3$
D
$3: 2$
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