1
COMEDK 2025 Evening Shift
MCQ (Single Correct Answer)
+1
-0

When $0.1 \mathrm{~mol} \mathrm{~L}^{-1}$ of KCl was filled in a Conductivity cell the resistance was 80 ohms at 298 K . (Conductivity of 0.1 M KCl at 298 K is $1.29 \mathrm{~S} \mathrm{~m}^{-1}$. The same cell when filled with an unknown electrolyte of concentration 0.025 M , had a resistance of 92 ohms. What is the Molar conductivity of the electrolyte at the given concentration?

A
$220.6 \mathrm{~S} \mathrm{~cm}^2 \mathrm{~mol}^{-1}$
B
$0.2206 \mathrm{~S} \mathrm{~cm}^2 \mathrm{~mol}^{-1}$
C
$448 \mathrm{~S} \mathrm{~cm}^2 \mathrm{~mol}^{-1}$
D
$0.449 \mathrm{~S} \mathrm{~cm}^2 \mathrm{~mol}^{-1}$
2
COMEDK 2025 Evening Shift
MCQ (Single Correct Answer)
+1
-0
An optically active compound $[\mathrm{X}]$ (Molecular formula $\mathrm{C}_8 \mathrm{H}_{11} \mathrm{~N}$ ) reacts with $\mathrm{CHCl}_3$ / Ethanolic KOH on heating to form an isocyanide. On reaction with $\mathrm{NaNO}_2 / \mathrm{HCl}$, it yields an alcohol with liberation of $\mathrm{N}_2$. Identify the compound $[\mathrm{X}]$.
A
2-Ethylaniline.
B
1-Phenylethanamine.
C
3, 4-Dimethylaniline.
D
2, 4-Dimethylaniline.
3
COMEDK 2025 Evening Shift
MCQ (Single Correct Answer)
+1
-0
Choose the correct statement from the options given
A
The decreasing order of basic nature of the following amines is: Methylamine $>$ Dimethylamine $>$ Trimethylamine $>$ Aniline.
B
The intermolecular bonding in primary amines is stronger than in secondary amines.
C
Benzene diazonium chloride when reacted with Aniline in presence of dil. HCl at 273 K yields $\mathrm{C}_6 \mathrm{H}_5-\mathrm{N}=\mathrm{N}-\mathrm{NH}-\mathrm{C}_6 \mathrm{H}_5$
D
On heating an aliphatic primary amine with $\mathrm{CHCl}_3$ in presence of Ethanolic KOH , a Nitrile is formed
4
COMEDK 2025 Evening Shift
MCQ (Single Correct Answer)
+1
-0
The number of electrons with azimuthal quantum numbers $l=1$ and $l=2$ for Cr in the ground state electronic configurations are respectively. [Given: $\mathrm{Cr}(\mathrm{Z}=24)$ ]
A
5 and 16
B
12 and 5
C
12 and 8
D
12 and 16
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