1
COMEDK 2025 Evening Shift
MCQ (Single Correct Answer)
+1
-0
Choose the incorrect statement.
A
Cresols are less acidic than Phenol because electron releasing groups do not favour formation of Phenoxide ion.
B
Ethanol acts as Nucleophile when the $\mathrm{O}-\mathrm{H}$ bond is broken and acts as Electrophile on getting protonated.
C
In the acid catalysed hydration of Ethene, an Oxonium ion is formed when it reacts with $\mathrm{H}_3 \mathrm{O}^{+}$and a Carbocation is formed when the Oxonium ion reacts with water.
D
In the reaction between Ethanol and Conc. $\mathrm{H}_2 \mathrm{SO}_4$ at 413 K , an Oxonium ion is formed when Ethanol gets protonated.
2
COMEDK 2025 Evening Shift
MCQ (Single Correct Answer)
+1
-0

Find the correct matches.

A. $\mathrm{Cr}_2 \mathrm{O}_7^{2-}$ P. is predominantly a basic compound.
B. $\mathrm{FeCr}_2 \mathrm{O}_4$ Q. is predominantly a acidic compound
C. $\mathrm{CrO}_3$ R. forms yellow chromate on reaction with $\mathrm{Na}_2 \mathrm{CO}_3$ in air.
D. $\mathrm{CrO}$ S. is interconvertible with $\mathrm{MO}_4^{2-}$ depending on the pH of the medium.

A
$\mathrm{A}=\mathrm{R} \quad \mathrm{B}=\mathrm{S} \quad \mathrm{C}=\mathrm{P} \quad \mathrm{D}=\mathrm{Q}$
B
$\mathrm{A}=\mathrm{S} \quad \mathrm{B}=\mathrm{R} \quad \mathrm{C}=\mathrm{P} \quad \mathrm{D}=\mathrm{Q}$
C
$\mathrm{A}=\mathrm{R} \quad \mathrm{B}=\mathrm{Q} \quad \mathrm{C}=\mathrm{S} \quad \mathrm{D}=\mathrm{P}$
D
$\mathrm{A}=\mathrm{S} \quad \mathrm{B}=\mathrm{R} \quad \mathrm{C}=\mathrm{Q} \quad \mathrm{D}=\mathrm{P}$
3
COMEDK 2025 Evening Shift
MCQ (Single Correct Answer)
+1
-0
Which of the following compounds has electrons symmetrically distributed in both $\mathrm{t}_{2 \mathrm{~g}}$ and $\mathrm{e}_{\mathrm{g}}$ orbitals?
A
$\left[\mathrm{CoF}_6\right]^{3-}$
B
$\left[M n(C N)_6\right]^{4-}$
C
$\left[\mathrm{Cr}\left(\mathrm{NH}_3\right)_6\right]^{3+}$
D
$\left[\mathrm{FeCl}_6\right]^{3-}$
4
COMEDK 2025 Evening Shift
MCQ (Single Correct Answer)
+1
-0

Identify the two incorrect electrochemical reactions shown as taking place in the given cells at the respective electrodes.

Cell Electrode Reaction
Lead-Storage Cell Cathode $\mathrm{Pb}+2 \mathrm{SO}_4{ }^{2-}+4 \mathrm{H}^{+}+2 \mathrm{e}^{-} \rightarrow \mathrm{PbSO}_4+2 \mathrm{H}_2 \mathrm{O}+\mathrm{SO}_2$
Leclanche Cell Cathode $\mathrm{MnO}_2+\mathrm{NH}_4^{+}+2 \mathrm{e}^{-} \rightarrow \mathrm{MnO}+\mathrm{OH}+\mathrm{NH}_3$
Mercury Cell Anode $\mathrm{Zn} / \mathrm{Hg}+2 \mathrm{OH}^{-} \rightarrow \mathrm{ZnO}(\mathrm{s})+\mathrm{H}_2 \mathrm{O}+2 \mathrm{e}^{-}$
Fuel Cell Cathode $\mathrm{O}_2(\mathrm{~g})+2 \mathrm{H}_2 \mathrm{O}+4 \mathrm{e}^{-} \rightarrow 4 \mathrm{OH}^{-}$

A
C & D
B
A & C
C
B & D
D
A & B
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