1
COMEDK 2025 Evening Shift
MCQ (Single Correct Answer)
+1
-0
Choose the incorrect statement from the following.
A
The energy difference between the staggered and eclipsed conformation of ethane is $12.55 \mathrm{~kJ} / \mathrm{mol}$
B
Staggered conformation of ethane is more stable than the eclipsed conformation.
C
The distance between non-bonded H -atoms of ethane in eclipsed conformation is $2.29$$$\mathop A\limits^o $$
D
A $90^{\circ}$ rotation converts staggered conformation of ethane into eclipsed conformation.
2
COMEDK 2025 Evening Shift
MCQ (Single Correct Answer)
+1
-0

Identify $[\mathrm{X}]$ used in the given reaction.

$[\mathrm{X}]+$ Copper $/ 573 \mathrm{~K} \rightarrow[\mathrm{Y}]$

$[\mathrm{Y}] \xrightarrow[\text { (ii) } \mathrm{H}_2 \mathrm{O} / \mathrm{H}^{+}]{\text {(i) } \mathrm{CH}_3 \mathrm{MgBr}}$ Tert.butyl alcohol. (major product)

A
Propan-1-ol
B
Butan-1-ol
C
Propan-2-ol
D
Butan-2-ol
3
COMEDK 2025 Evening Shift
MCQ (Single Correct Answer)
+1
-0

Which one of the following is the product $(\mathrm{Z})$ formed at the end of the given reaction:

$$\begin{aligned} & \text { Propan-1-ol }+\mathrm{SOCl}_2 \rightarrow[\mathrm{X}] \\ & {[\mathrm{X}]+\mathrm{HC} \equiv \mathrm{C}-\mathrm{Na} \rightarrow[\mathrm{Y}]} \\ & {[\mathrm{Y}]+\mathrm{H}_2 \mathrm{SO}_4 / \mathrm{HgSO}_4, 330 \mathrm{~K} \rightarrow[\mathrm{Z}]} \end{aligned}$$

A
Pentan-2-ol.
B
Pent-2-ene.
C
Pentanal.
D
Pentan-2-one.
4
COMEDK 2025 Evening Shift
MCQ (Single Correct Answer)
+1
-0

Two statements, one Assertion and the other Reason are given. Identify the correct option

Assertion : Primary and secondary amides on treatment with $\mathrm{Br}_2$ and alcoholic NaOH yield primary and secondary amines respectively and the reaction involves stepping down the series.

Reason : The reaction occurs due to the migration of alkyl group from Carbonyl carbon atom to the Nitrogen atom with elimination of carbonyl group as the carbonate salt.

A
Assertion is correct but Reason is incorrect.
B
Both Assertion and Reason are incorrect.
C
Both Assertion and Reason are correct.
D
Assertion is incorrect but Reason is correct.
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