1
COMEDK 2025 Evening Shift
MCQ (Single Correct Answer)
+1
-0
For the cell reaction $4 \mathrm{Br}^{-}+\mathrm{O}_2+4 \mathrm{H}^{+} \rightarrow 2 \mathrm{Br}_2+2 \mathrm{H}_2 \mathrm{O}$ at 298 K , the $\mathrm{E}^0$ cell $=0.16 \mathrm{~V}$. What would be the $\mathrm{K}_{\mathrm{c}}$ (Equilibrium constant) value if the reverse reaction were to take place?
A
$2.012 \times 10^{-10}$
B
$8.47 \times 10^{-9}$
C
$1.422 \times 10^{-11}$
D
$7.031 \times 10^{-10}$
2
COMEDK 2025 Evening Shift
MCQ (Single Correct Answer)
+1
-0
The bond angles in the following molecules decreases in the order. $\mathrm{BF}_3, \mathrm{NH}_3, \mathrm{PF}_3$ and $\mathrm{XeF}_2$
A
$\mathrm{NH}_3>P F_3>X e F_2>B F_3$
B
$\mathrm{XeF}_2>\mathrm{BF}_3>\mathrm{NH}_3>\mathrm{PF}_3$
C
$\mathrm{BF}_3>\mathrm{NH}_3>\mathrm{XeF}_2>\mathrm{PF}_3$
D
$P F_3>B F_3>N H_3>X e F_2$
3
COMEDK 2025 Evening Shift
MCQ (Single Correct Answer)
+1
-0

Two statements, one Assertion and the other Reason, are given. Choose the correct option.

Assertion : During the electrolysis of aqueous $\mathrm{NaCl}, \mathrm{Cl}_2$ is liberated at the anode in preference to $\mathrm{O}_2$ and water gets reduced to $\mathrm{H}_2$ at cathode.

Reason : The reaction at Anode with lower oxidation potential is not preferred due to over potential of Oxygen.

A
Both Assertion and Reason are incorrect.
B
Both Assertion and Reason are correct.
C
Assertion is correct but Reason is incorrect.
D
Assertion is incorrect but Reason is correct.
4
COMEDK 2025 Evening Shift
MCQ (Single Correct Answer)
+1
-0
An aqueous solution of volume V ml contains a non-volatile solute of unknown mass $W_B \mathrm{~g}$ and molar mass $M_B \mathrm{~g} / \mathrm{mol}$. If the Osmotic pressure of the solution is 1.013 bar, which one of the following is the mathematical expression to be used to calculate $W_B$ ?
A
$W_B=\frac{\pi \mathrm{M}_{\mathrm{B}} V}{760 * \mathrm{RT} * 1000}$
B
$W_B=\frac{\pi \mathrm{M}_{\mathrm{B}} V 1000}{76 \mathrm{RT}}$
C
$W_B=\frac{\pi \mathrm{M}_{\mathrm{B}} V}{\mathrm{RT}}$
D
$W_B=\frac{\pi \mathrm{M}_{\mathrm{B}} V}{1000 \mathrm{RT}}$
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