1
COMEDK 2025 Evening Shift
MCQ (Single Correct Answer)
+1
-0

Identify the Carbonyl compound which will not be formed when hydration of Alkynes is carried out with dil. $\mathrm{H}_2 \mathrm{SO}_4 / \mathrm{Hg}^{2+}$ at 333 K .

Acetone, Butanal, Ethanal, Butanone.

A
Acetone
B
Butanone
C
Butanal
D
Ethanal
2
COMEDK 2025 Evening Shift
MCQ (Single Correct Answer)
+1
-0
Choose the incorrect statement from the following.
A
The energy difference between the staggered and eclipsed conformation of ethane is $12.55 \mathrm{~kJ} / \mathrm{mol}$
B
Staggered conformation of ethane is more stable than the eclipsed conformation.
C
The distance between non-bonded H -atoms of ethane in eclipsed conformation is $2.29$$$\mathop A\limits^o $$
D
A $90^{\circ}$ rotation converts staggered conformation of ethane into eclipsed conformation.
3
COMEDK 2025 Evening Shift
MCQ (Single Correct Answer)
+1
-0

Identify $[\mathrm{X}]$ used in the given reaction.

$[\mathrm{X}]+$ Copper $/ 573 \mathrm{~K} \rightarrow[\mathrm{Y}]$

$[\mathrm{Y}] \xrightarrow[\text { (ii) } \mathrm{H}_2 \mathrm{O} / \mathrm{H}^{+}]{\text {(i) } \mathrm{CH}_3 \mathrm{MgBr}}$ Tert.butyl alcohol. (major product)

A
Propan-1-ol
B
Butan-1-ol
C
Propan-2-ol
D
Butan-2-ol
4
COMEDK 2025 Evening Shift
MCQ (Single Correct Answer)
+1
-0

Which one of the following is the product $(\mathrm{Z})$ formed at the end of the given reaction:

$$\begin{aligned} & \text { Propan-1-ol }+\mathrm{SOCl}_2 \rightarrow[\mathrm{X}] \\ & {[\mathrm{X}]+\mathrm{HC} \equiv \mathrm{C}-\mathrm{Na} \rightarrow[\mathrm{Y}]} \\ & {[\mathrm{Y}]+\mathrm{H}_2 \mathrm{SO}_4 / \mathrm{HgSO}_4, 330 \mathrm{~K} \rightarrow[\mathrm{Z}]} \end{aligned}$$

A
Pentan-2-ol.
B
Pent-2-ene.
C
Pentanal.
D
Pentan-2-one.
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