1
COMEDK 2025 Evening Shift
MCQ (Single Correct Answer)
+1
-0

Consider the following reaction

$$\text { Propyne }+\mathrm{CH}_3 \mathrm{MgBr} \xrightarrow{\text { dry ether }} \mathbf{X}$$

Identify ' X ' from the following.

A
But-2-yne
B
Propane
C
Methane
D
But-2-ene
2
COMEDK 2025 Evening Shift
MCQ (Single Correct Answer)
+1
-0

Match the IUPAC names in Column II with the correct structures given in Column I.

Structures of compounds IUPAC name
A COMEDK 2025 Evening Shift Chemistry - IUPAC Nomenclatures Question 1 English 1 P 1-Bromomethyl-3-(2,2-dimethylpropyl)benzene
B COMEDK 2025 Evening Shift Chemistry - IUPAC Nomenclatures Question 1 English 2 Q 1-Bromo-4-(1-methylethyl)benzene
C COMEDK 2025 Evening Shift Chemistry - IUPAC Nomenclatures Question 1 English 3 R 1-Bromo-2-(1-methylpropyl)benzene
D COMEDK 2025 Evening Shift Chemistry - IUPAC Nomenclatures Question 1 English 4 S 1-Bromo-4-(2-methylpropyl)benzene

A
$\mathrm{A}=\mathrm{R} \quad \mathrm{B}=\mathrm{P} \quad \mathrm{C}=\mathrm{S} \quad \mathrm{D}=\mathrm{Q}$
B
$\mathrm{A}=\mathrm{S} \quad \mathrm{B}=\mathrm{R} \quad \mathrm{C}=\mathrm{Q} \quad \mathrm{D}=\mathrm{P}$
C
$\mathrm{A}=\mathrm{Q} \quad \mathrm{B}=\mathrm{P} \quad \mathrm{C}=\mathrm{S} \quad \mathrm{D}=\mathrm{R}$
D
$\mathrm{A}=\mathrm{S} \quad \mathrm{B}=\mathrm{R} \quad \mathrm{C}=\mathrm{P} \quad \mathrm{D}=\mathrm{Q}$
3
COMEDK 2025 Evening Shift
MCQ (Single Correct Answer)
+1
-0
An organic compound $[\mathrm{X}]$ (Molecular formula $\mathrm{C}_6 \mathrm{H}_{12} \mathrm{O}_2$ ) reacts with dil. $\mathrm{H}_2 \mathrm{SO}_4$ to form an alcohol [B] and a carboxylic acid [C]. Reaction of compound $[\mathrm{B}]$ with Jones reagent yielded compound $[\mathrm{C}]$. When compound $[\mathrm{C}]$ was heated with $\mathrm{P}_2 \mathrm{O}_5$ an Anhydride was formed. Compound $[\mathrm{X}]$ is ------------- --
A
$\mathrm{C}_2 \mathrm{H}_5-\mathrm{COO}-\left(\mathrm{CH}_2\right)_2-\mathrm{CH}_3$
B
$\mathrm{CH}_3-\mathrm{COO}-\left(\mathrm{CH}_2\right)_3-\mathrm{CH}_3$
C
$\mathrm{CH}_3-\mathrm{COO}-\mathrm{CH}_2-\mathrm{CH}-\left(\mathrm{CH}_3\right)_2$
D
$\mathrm{CH}_3-\mathrm{COO}-\mathrm{C}-\left(\mathrm{CH}_3\right)_3$
4
COMEDK 2025 Evening Shift
MCQ (Single Correct Answer)
+1
-0
In the decomposition of limestone to lime, the values of $\Delta H^o$ and $\Delta S^o$ are $+179.1 \mathrm{~kJ} \mathrm{~mol}^{-1}$ and $160.2 \mathrm{~J} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}$. Calculate the temperature above which conversion of limestone to lime will be spontaneous, if values of $\Delta H^o$ and $\Delta S^o$ remain unchanged with temperature. [Assuming pressure 1 bar ]
A
1018 K
B
1200 K
C
1028 K
D
1118 K
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