1
COMEDK 2025 Afternoon Shift
MCQ (Single Correct Answer)
+1
-0
Identify the incorrect statement.
A
When (一)-2-bromooctane is reacted with aqueous KOH , the substitution follows $\mathrm{S}_{\mathrm{N}} 2$ mechanism and product formed is (一) -Octan-2-ol.
B
Benzylic halides show higher reactivity towards $S_N 1$ reaction.
C
The reaction of $\mathrm{C}_6 \mathrm{H}_5 \mathrm{CH}_2-\mathrm{CHCl}-\mathrm{C}_6 \mathrm{H}_5$ with alc. KOH on heating yields two products.
D
Optically active (-)-2-Methylbutan-1-ol on reaction with HCl yields a product $(+)$-1-Chloro-2-methylbutane.
2
COMEDK 2025 Afternoon Shift
MCQ (Single Correct Answer)
+1
-0
Arrange the following ions in the decreasing order of covalent double bonds formed by the transition metal with oxygen.

A. $=$ chromate $\mathrm{B}=$ permanganate $\mathrm{C}=$ dichromate

A
$\mathrm{A}>\mathrm{B}>\mathrm{C}$
B
$\mathrm{B}>\mathrm{C}>\mathrm{A}$
C
$\mathrm{B}>\mathrm{A}>\mathrm{C}$
D
$\mathrm{C}>\mathrm{B}>\mathrm{A}$
3
COMEDK 2025 Afternoon Shift
MCQ (Single Correct Answer)
+1
-0

Which one of the following structures in Column I does not have the correct IUPAC name as given in Column II.

S.No. Structure IUPAC name
A. $\left[\mathrm{CoBr}_2(\mathrm{en})_2\right] \mathrm{Cl}$ P. Dibromidodi-( ethan-1, 2 - diamine)cobalt (III) chloride
B. $\mathrm{Na}\left[\mathrm{PtBrCl}\left(\mathrm{NO}_2\right)\left(\mathrm{NH}_3\right)\right]$ Q. Sodium amminebromidochloridonitrito- N - palatinate(II)
C. $\left[\mathrm{Cr}\left(\mathrm{H}_2 \mathrm{O}\right)_2\left(\mathrm{NH}_3\right)_4 \mathrm{Cl}\right] \mathrm{SO}_4$ R. Tetraamminediaquachloridochromium (III) sulphate.
D. $\left[\mathrm{Pt}\left(\mathrm{NH}_3\right)_4\right]\left[\mathrm{PtCl}_4\right]$ S. Tetraammineplatinum (II) tetrachloridoplatinate (II)

A
B
B
A
C
D
D
C
4
COMEDK 2025 Afternoon Shift
MCQ (Single Correct Answer)
+1
-0
When $0.4 \mathrm{~g} \mathrm{CH}_3 \mathrm{COOH}$ is added to 40 g of Benzene to form a solution, the freezing point is depressed by $0.45^{\circ} \mathrm{C}$. If Acetic acid undergoes dimerisation in Benzene ( $\mathrm{K}_{\mathrm{f}}=5.12 \mathrm{~K} \mathrm{~kg} / \mathrm{mol}$ ) what is the percentage association of the acid in Benzene?
A
50.12
B
47.2
C
94.54
D
20.10
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