1
COMEDK 2025 Afternoon Shift
MCQ (Single Correct Answer)
+1
-0
An organic compound $\mathrm{A}\left(\mathrm{C}_5 \mathrm{H}_9 \mathrm{~N}\right)$ upon reaction with $\mathrm{Na} / \mathrm{Hg} / \mathrm{C}_2 \mathrm{H}_5 \mathrm{OH}$ gives compound B . B reacts with $\mathrm{NaNO}_2 / \mathrm{HCl}$ at 274 K to form C with quantitative liberation of $\mathrm{N}_2$ gas. B also reacts with Hinsberg's reagent to form a compound which is soluble in alkali. Identify compound B.
A
$\left[\left(\mathrm{CH}_3\right)_3-\mathrm{N}-\mathrm{CH}_2 \mathrm{CH}_3\right]^{+}$
B
$\mathrm{CH}_3-\left(\mathrm{CH}_2\right)_3-\mathrm{NH}-\mathrm{CH}_3$
C
$\mathrm{CH}_3-\left(\mathrm{CH}_2\right)_4-\mathrm{NH}_2$
D
$\mathrm{CH}_3-\left(\mathrm{CH}_2\right)_2-\mathrm{N}-\left(\mathrm{CH}_3\right)_2$
2
COMEDK 2025 Afternoon Shift
MCQ (Single Correct Answer)
+1
-0

The $E_{M^{3+} / M^{2+}}^o$ values for $\mathrm{Cr}, \mathrm{Mn}, \mathrm{Fe}$ and Co are $-0.41,+1.57,+0.77$ and +1.97 V respectively.

For which of these metals, the change in oxidation state from +2 to +3 is the easiest?

A
Fe
B
Mn
C
Cr
D
Co
3
COMEDK 2025 Afternoon Shift
MCQ (Single Correct Answer)
+1
-0
Given are 4 pairs of covalent molecules. Identify the pair in which both molecules have the same shape.
A
$\mathrm{XeF}_2 ~\&~ \mathrm{HgCl}_2$
B
$\mathrm{BF}_3~ \& ~\mathrm{NH}_3$
C
$\mathrm{XeF} 4 ~\& ~\mathrm{SF}_4$
D
$\mathrm{BrF}_5 ~\& ~\mathrm{PCl}_5$
4
COMEDK 2025 Afternoon Shift
MCQ (Single Correct Answer)
+1
-0
Lead storage battery contains $4.25 \mathrm{M} \mathrm{H}_2 \mathrm{SO}_4$ which has a density of $1.24 \mathrm{~g} / \mathrm{ml}$. Calculate the molality of aqueous solution of $\mathrm{H}_2 \mathrm{SO}_4$.
A
6.264
B
3.427
C
5.161
D
4.108
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