1
COMEDK 2025 Afternoon Shift
MCQ (Single Correct Answer)
+1
-0
Choose the correct statement:
A
Aliphatic amines are weaker bases than $\mathrm{NH}_3$ while aromatic amines are stronger bases than $\mathrm{NH}_3$.
B
Gabriel phthalimide synthesis is used for preparing both Ethyl amine and Aniline.
C
Anilinium ion is less resonance stabilised than Aniline.
D
Sec-butylamine is optically inactive because Nitrogen atom of the $-\mathrm{NH}_2$ group is achiral.
2
COMEDK 2025 Afternoon Shift
MCQ (Single Correct Answer)
+1
-0
A transition metal M forms 4 homoleptic octahedral coordination compounds, $\mathrm{A}, \mathrm{B}, \mathrm{C}$ and D of the type $\left[\mathrm{MX}_6\right]^{z-}$ with monodentate ligands a, b, c and d respectively. These compounds absorb red. blue. yellow and blue-green light respectively. Which one of the options shows the correct order of decreasing ligand strength?
A
$\mathrm{B}>\mathrm{D}>\mathrm{C}>\mathrm{A}$
B
$\mathrm{D}>\mathrm{C}>\mathrm{B}>\mathrm{A}$
C
$\mathrm{A}>\mathrm{C}>\mathrm{D}>\mathrm{B}$
D
$\mathrm{A}>\mathrm{B}>\mathrm{C}>\mathrm{D}$
3
COMEDK 2025 Afternoon Shift
MCQ (Single Correct Answer)
+1
-0
Which one of the following is the correct statement?
A
Fructose exists as a five membered ring named furanose.
B
Glucose gives Saccharic acid on reaction with $\mathrm{Br}_2$ water.
C
Amylose is a water insoluble branched chain polymer of $\alpha-D-(-)$-glucose.
D
Cellulose is a branched chain polysaccharide having only $\propto$-D-glucose units.
4
COMEDK 2025 Afternoon Shift
MCQ (Single Correct Answer)
+1
-0

(i) and (ii) are 2 chemical reactions carried out at TK.

(i). $\mathrm{X} \rightarrow \mathrm{Y}+\mathrm{W}$ with $\mathrm{k}_1$ as rate constant.

(ii). $\mathrm{X} \rightarrow \mathrm{Z}+\mathrm{W}$ with $k_2$ as rate constant.

The Activation energy for reaction (ii) is 3 times that of reaction (i). What is the expression for $k_1$ ?

A
$k_1=-2 k_2 e^{2 E a_1 / R T}$
B
$k_1=k_2 e^{2 E a_1 / R T}$
C
$k_1=2 k_2 e^{E a_1 / R T}$
D
$k_1=k_2 / 2 e^{-E a_1 / R T}$
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