1
COMEDK 2025 Afternoon Shift
MCQ (Single Correct Answer)
+1
-0
Choose the incorrect statement.
A
The increasing order of boiling points of 5 compounds having comparable molar masses is as follows: Methoxyethane $<$ Propanone $<$ Propanal $<$ Propan-1-ol
B
During nucleophilic addition of HCN to RCHO , the hybridisation changes from $\mathrm{sp}^2$ to $\mathrm{sp}^3$ and a tetrahedral intermediate is formed.
C
Acetone undergoes Wolff Kishner reaction to yield Propane.
D
The order of reactivity towards Nucleophilic attack is Methanal $>$ Di-tert.butyl ketone $>$ Benzaldehyde $>$ Acetophenone
2
COMEDK 2025 Afternoon Shift
MCQ (Single Correct Answer)
+1
-0

Match A, B, C and D with the appropriate functions given.

Column I Functions
A. Oxidoreductase P. Malfunctioning leads to Addison's disease.
B. Phosphodiester bonds Q. Regulates responses to external stimuli.
C. Adrenal cortex R. Catalyses glycolysis.
D. Epinephrine S. Links nucleotides together.

A
$\mathrm{A}=\mathrm{R} \quad \mathrm{B}=\mathrm{S} \quad \mathrm{C}=\mathrm{Q} \quad \mathrm{D}=\mathrm{P}$
B
$\mathrm{A}=\mathrm{R} \quad \mathrm{B}=\mathrm{S} \quad \mathrm{C}=\mathrm{P} \quad \mathrm{D}=\mathrm{Q}$
C
$\mathrm{A}=\mathrm{R} \quad \mathrm{B}=\mathrm{P} \quad \mathrm{C}=\mathrm{S} \quad \mathrm{D}=\mathrm{Q}$
D
$\mathrm{A}=\mathrm{Q} \quad \mathrm{B}=\mathrm{R} \quad \mathrm{C}=\mathrm{S} \quad \mathrm{D}=\mathrm{P}$
3
COMEDK 2025 Afternoon Shift
MCQ (Single Correct Answer)
+1
-0

Two statements, One Assertion and the other Reason, are given.

Which one of the following is the correct option?

Assertion: The acid strength of 4 compounds in the descending order is p- Nitrophenol > p-Methoxyphenol > Phenol > p-chlorophenol.

Reason: Electron withdrawing groups increase the acid strength while Electron donating groups decrease the acid strength of Phenol and its derivatives.

A
Assertion is correct but Reason is wrong.
B
Both Assertion and Reason are wrong.
C
Assertion is wrong but Reason is correct.
D
Both Assertion and Reason are correct.
4
COMEDK 2025 Afternoon Shift
MCQ (Single Correct Answer)
+1
-0
Identify the incorrect statement.
A
When (一)-2-bromooctane is reacted with aqueous KOH , the substitution follows $\mathrm{S}_{\mathrm{N}} 2$ mechanism and product formed is (一) -Octan-2-ol.
B
Benzylic halides show higher reactivity towards $S_N 1$ reaction.
C
The reaction of $\mathrm{C}_6 \mathrm{H}_5 \mathrm{CH}_2-\mathrm{CHCl}-\mathrm{C}_6 \mathrm{H}_5$ with alc. KOH on heating yields two products.
D
Optically active (-)-2-Methylbutan-1-ol on reaction with HCl yields a product $(+)$-1-Chloro-2-methylbutane.
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