An aromatic hydrocarbon $$[\mathrm{A}]\left(\mathrm{Molecular}\right.$$ formula $$\left.\mathrm{C}_9 \mathrm{H}_{12}\right)$$, undergoes air oxidation followed by reaction with dil. $$\mathrm{HCl}$$ to give [B] as one of the products
Compound [B] forms a white precipitate on treatment with $$\mathrm{Br}_2(\mathrm{aq})$$
Sodium salt of [B] reacts with $$\mathrm{CO}_2$$ at $$400 \mathrm{~K}$$ under high pressure followed by acid hydrolysis to give [C]
Compound [C] reacts with acetic anhydride / conc. $$\mathrm{H}_2 \mathrm{SO}_4$$ to form [D] Identify compound $$[\mathrm{D}]$$
A given chemical reaction is represented by the following stoichiometric equation.
$$3 X+2 Y+\frac{5}{2} Z \rightarrow P_1+P_2+P_3$$
The rate of reaction can be expressed as _________.
Match the chemical reactions taking place at the Anode of the cell with the correct cell in which the reaction occurs.
No. | Anodic reaction | No. | Cell |
---|---|---|---|
A | $$ \mathrm{Zn}(\mathrm{Hg})+2 \mathrm{OH}^{-} \rightarrow \mathrm{ZnO}_{(\mathrm{S})}+\mathrm{H}_2 \mathrm{O}+2 e $$ |
P | Fuel cell |
B | $$ 2 \mathrm{H}_2(g)+4 \mathrm{OH}^{-} \rightarrow 4 \mathrm{H}_2 \mathrm{O}(l)+4 e $$ |
Q | Leclanche cell |
C | $$ Z n_{(S)} \rightarrow Z n^{2+}+2 e $$ |
R | Nickel Cadmium storage cell |
D | $$ \mathrm{Cd}_{(S)}+2 \mathrm{OH}^{-} \rightarrow \mathrm{CdO}_{(S)}+\mathrm{H}_2 \mathrm{O}(l)+2 e $$ |
S | Mercury cell |
If the enthalpy of formation of a diatomic molecule $$\mathrm{AB}$$ is $$-400 \mathrm{~kJ} / \mathrm{mol}$$ and the bond dissociation energies of $$\mathrm{A}_2$$ and $$\mathrm{B}_2$$ and $$\mathrm{AB}$$ are in the ratio $$2: 1: 2$$, what is the bond dissociation enthalpy of $$\mathrm{B}_2$$ ?