For the reaction $$\mathrm{Cl}_{2(\mathrm{~g})}+2 \mathrm{NO}_{(\mathrm{g})} \rightarrow 2 \mathrm{NOCl}_{(\mathrm{g})}$$, the following data was obtained:
Experiment No. | Initial concentration of $$\mathrm{Cl_2}$$ ($$\mathrm{M}$$) | Initial concentration of $$\mathrm{NO}$$ ($$\mathrm{M}$$) | Initial reaction rate ($$\mathrm{M}$$/min) |
---|---|---|---|
I | 0.15 | 0.15 | 0.60 |
II | 0.30 | 0.15 | 1.20 |
III | 0.15 | 0.3 | 2.40 |
IV | 0.25 | 0.25 | 2.78 |
Identify the order of the reaction with respect to $$\mathrm{Cl}_2, \mathrm{NO}$$ and the value of Rate constant.
$$\mathrm{K}_{\mathrm{H}}$$ for $$\mathrm{O}_2$$ at $$293 \mathrm{~K}$$ is $$34.86 \mathrm{~kbar}$$. What should be the partial pressure of $$\mathrm{O}_2$$ gas so that it has a solubility of $$0.08 \mathrm{~g} / \mathrm{L}$$ in water at $$293 \mathrm{~K}$$ ? (Density of solution $$=1 \mathrm{~g} / \mathrm{ml}$$)
The permanganate ion in acid medium acts as an oxidant and gets converted to its lower oxidation state. What would be the spin only magnetic moment of such reduced manganese ion?
$$\mathrm{A}_3 \mathrm{~B}_4$$ is a sparingly soluble salt with a solubility of $$\mathrm{s} g / \mathrm{L}$$. If the Molar mass of $$\mathrm{A}_3 \mathrm{~B}_4$$ is $$\mathrm{Mg} / \mathrm{mol}$$, what is the expression for its $$\mathrm{K}_{\text {sp }}$$ ?